19643-70-0Relevant articles and documents
Tuning the peri effect for enantioselectivity: Asymmetric hydrogenation of unfunctionalized olefins with the BIPI ligands
Busacca, Carl A.,Qu, Bo,Gret, Nicole,Fandrick, Keith R.,Saha, Anjan K.,Marsini, Maurice,Reeves, Diana,Haddad, Nizar,Eriksson, Magnus,Wu, Jiang-Ping,Grinberg, Nelu,Lee, Heewon,Li, Zhibin,Lu, Bruce,Chen, Dajun,Hong, Yaping,Ma, Shengli,Senanayake, Chris H.
, p. 1455 - 1463 (2013)
The modular nature of the BIPI ligands allows for systematic optimization of each ligand region. The development of ligands optimized for asymmetric hydrogenation of the challenging unfunctionalized olefin substrate class is described. The naphthyl peri p
Improved synthesis of cyclohexane-backbone iridium-complexes of quinoline-phosphine and their applications in asymmetric hydrogenation
Liu, Qibin
, (2020/09/15)
– The iridium-complexes 3 and 4 with cyclohexane-backbone derived from quinoline were easily synthesized. The key step is cis/trans stereoselective reduction of 2-(quinolin-2-yl)cyclohexanone 5 to trans-2-(quinolin-2-yl)cyclohexanol 6 using Al(Oi-Pr)3/i-P
Tetrahydroquinoline skeleton chiral phosphine-nitrogen ligand and preparation method and application thereof
-
Paragraph 0184-0189, (2020/11/10)
The invention relates to the field of asymmetric catalytic hydrogenation, in particular to a tetrahydroquinoline skeleton chiral phosphine-nitrogen ligand and a preparation method and application thereof. The tetrahydroquinoline skeleton chiral phosphine-