19654-17-2

Basic information

• Product Name: Benzothiazole, 2-[(phenylmethyl)thio]-
• Synonyms: Benzothiazole, 2-[(phenylmethyl)thio]-;2-(benzylthio)benzo[d]thiazole;2-BENZYLSULFANYLBENZOTHIAZOLE;2-(benzylsulfanyl)-1,3-benzothiazole
• CAS NO: 19654-17-2
• Molecular Formula: C₁₄H₁₁NS₂
• Molecular Weight: 257.37384
• Mol File: 19654-17-2.mol
• Article Data: 58

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzothiazole, 2-[(phenylmethyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzothiazole, 2-[(phenylmethyl)thio]-(19654-17-2)
• EPA Substance Registry System: Benzothiazole, 2-[(phenylmethyl)thio]-(19654-17-2)

Safety Data

• Hazardous Substances Data: 19654-17-2(Hazardous Substances Data)

Usage

General Description

Benzothiazole, 2-[(phenylmethyl)thio]- is a chemical compound with the molecular formula C15H13NS and a molecular weight of 243.34 g/mol. It is a yellow to amber colored liquid with a faint odor. This chemical is commonly used in the production of rubber additives, dyes, and pharmaceuticals. It is also used in the synthesis of antioxidants and fungicides. Benzothiazole, 2-[(phenylmethyl)thio]- is known to have potential health hazards and should be handled with care in a laboratory or industrial setting.

Upstream product

• 7778-70-3 potassium 2-mercaptobenzothiazolate 
• 100-44-7 benzyl chloride 
• 6011-99-0 benzo[d]thiazol-2-yl thiocyanate 
• 1589-82-8 phenylmagnesium bromide 
• 149-30-4 2-Mercaptobenzothiazole 
• 103-83-3 N,N'-dimethylbenzylamine 
• 27691-43-6 1-(benzylsulphanyl)-4-Nitrobenzene 
• 100-39-0 benzyl bromide 
• 95-16-9 1,3-Benzothiazole 
• 6313-36-6 benzyl thiosulphate 
• 260783-80-0 N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate 
• 97-74-5 bis(dimethylthiocarbamoyl)sulfide 
• 137-07-5 2-amino-benzenethiol 
• 100-51-6 benzyl alcohol 

Downstream Products

• 149-30-4 2-thioxo-3H-1,3-benzothiazole 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 33682-61-0 3-benzylbenzo[d]thiazole-2(3H)-thione 
• 67219-33-4 2-phenylmethanesulfonyl-benzothiazole 
• 886206-84-4 1,3-benzothiazol-2-yl (phenyl)fluoromethyl sulfone 
• 133512-86-4 ((1Z,3E)-1-fluorobuta-1,3-diene-1,4-diyl)dibenzene 
• 3846-66-0 (E)-1-tert-butyl-2-phenylethene 
• 4714-21-0 E-1-methyl-4-styryl-benzene 
• 68036-69-1 (E)-2-methyl-4-phenyl-1,3-butadiene 
• 1608-31-7 (cyclohexylidenemethyl)benzene 
• 39491-73-1 (E)-(4-methylpenta-1,3-dien-1-yl)benzene 
• 15325-56-1 (Z)-3-methyl-1-phenylbut-1-ene 
• 15325-61-8 (E)-(3-methylbut-1-en-1-yl)benzene 

Relevant articles and documents

Facile synthesis of 2-(substitutedbenzylsulfanyl)-benzothiazoles and their antimicrobial activity screening

A simple and convenient procedure for the preparation of 2-(substitutedbenzylsulfanyl)benzothiazoles by the reaction of 2-mercaptobenzothiazole and benzyl bromides in acetone/K2CO 3 has been reported and the compounds have been scree

Preparation of alkyl aryl sulfides from alcohols and 2- sulfanylbenzothiazole by a new type of oxidation-reduction condensation using aryl diphenylphosphinite and benzoquinone derivatives

A method for the preparation of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite and 2.6-dimethoxy-1,4-benzoquinone is described. In this reaction, the chiral alcohols are converted into the corresponding chiral sulfides with almost complete inversion of configurations under mild and neutral conditions. Copyright

Ag-Cu copromoted direct C2-H bond thiolation of azoles with Bunte salts as sulfur sources

A direct C2-H thiolation of azoles with Bunte salts was achieved under the combined action of copper and silver salts. This protocol could furnish various substituted 2-thioazoles in moderate to good yields. This method has a broad substrate scope and shows good functional group tolerance.

Three-Component Synthesis of 2-Substituted Thiobenzoazoles Using Tetramethyl Thiuram Monosulfide (TMTM) as Thiocarbonyl Surrogate

A metal-free synthesis of 2-benzyl/allyl-substituted thiobenzoazoles was developed starting from tetramethyl thiuram monosulfide (TMTM) which served as thiocarbonyl surrogate. By using 2-aminophenols (or 2-aminothiophenols, or 1,2-phenylenediamines) and TMTM as starting materials, 2-mercaptobenzoazoles could be synthesized efficiently. The subsequent C–S bond formation with benzyl/allyl halides gave the final products (2-benzyl/allyl-substituted thiobenzoazoles) with good to excellent yields. The metal-free conditions, inexpensive and easily available starting materials, and broad substrate scope are the advantageous features of this protocol.