201135-88-8

Basic information

• Product Name: CH(CH₂)6NH⁽¹⁺⁾*[Sn(C₆H₅)3(N₃)2]^(1-)=CH(CH₂)6NH[Sn(C₆H₅)3(N₃)2]
• CAS NO: 201135-88-8
• Molecular Weight: 546.262
• Mol File: 201135-88-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CH(CH₂)6NH⁽¹⁺⁾*[Sn(C₆H₅)3(N₃)2]^(1-)=CH(CH₂)6NH[Sn(C₆H₅)3(N₃)2](CAS DataBase Reference)
• NIST Chemistry Reference: CH(CH₂)6NH⁽¹⁺⁾*[Sn(C₆H₅)3(N₃)2]^(1-)=CH(CH₂)6NH[Sn(C₆H₅)3(N₃)2](201135-88-8)
• EPA Substance Registry System: CH(CH₂)6NH⁽¹⁺⁾*[Sn(C₆H₅)3(N₃)2]^(1-)=CH(CH₂)6NH[Sn(C₆H₅)3(N₃)2](201135-88-8)

Safety Data

• Hazardous Substances Data: 201135-88-8(Hazardous Substances Data)

Upstream product

• 100-76-5 Quinuclidine 
• 1158-51-6 triphenyltin azide 

Relevant articles and documents

Piperidinium diazidotriphenylstannate and quinuclidinium diazidotriphenylstannate

Two triphenyltin-azide adducts with cyclic aliphatic amines are shown by X-ray diffraction to be [LH][(C6H5)3Sn(N3)2], where for (I), L = piperidine (C5H11N), and for (II), L = quinuclidine (C7H13N). The anions have quasi-trigonal-bipyramidal symmetry, with the azide groups occupying axial positions. In each case, the azide groups are non-equivalent due to one of them hydrogen bonding with the cation. In (I), the NH2 of the cation hydrogen bonds with azides of adjacent anions forming chains through the lattice. For (II), the asymmetric unit has two cations and anions. One cation singly hydrogen bonds to an azide group of one anion, while the other cation forms a bifurcated hydrogen bond linked to azide groups on the two different anions. The cations have their usual geometries, the piperidinium ion having the expected chair conformation.