203000-48-0 Usage
General Description
(S,S)-1,2-Bis[(tert-butyl)methylphosphino]ethane bis(borane) is a chemical compound used as a reagent and catalyst in various chemical reactions. It consists of two phosphine ligands attached to a borane backbone. (S,S)-1,2-BIS[(TERT-BUTYL)METHYLPHOSPHINO]ETHANE BIS(BORANE) is air and moisture sensitive, and its borane groups are able to react with a variety of functional groups under mild conditions. It has been used in asymmetric hydrogenation reactions and as a reducing agent in organic synthesis. Additionally, it exhibits high thermal stability and can be easily handled in a laboratory setting. Overall, (S,S)-1,2-Bis[(tert-butyl)methylphosphino]ethane bis(borane) is an important reagent in organometallic chemistry and has applications in both academic and industrial research.
Check Digit Verification of cas no
The CAS Registry Mumber 203000-48-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,0,3,0,0 and 0 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 203000-48:
(8*2)+(7*0)+(6*3)+(5*0)+(4*0)+(3*0)+(2*4)+(1*8)=50
50 % 10 = 0
So 203000-48-0 is a valid CAS Registry Number.
InChI:InChI=1/C12H28P2.2BH3/c1-11(2,3)13(7)9-10-14(8)12(4,5)6;;/h9-10H2,1-8H3;2*1H3/t13-,14-;;/m0../s1
203000-48-0Relevant articles and documents
Stereospecific construction of a trans-1,4-diphosphacyclohexane skeleton
Morisaki, Yasuhiro,Imoto, Hiroaki,Ouchi, Yuko,Nagata, Yuuya,Chujo, Yoshiki
supporting information; experimental part, p. 1489 - 1492 (2009/05/11)
(Chemical Equation Presented) trans-1,4-Diphosphacyclohexanes were successfully synthesized by the stereospecific intramolecular coupling reaction of the optically active bisphosphine. This is a new route for the construction of the trans-1,4-diphosphacyclohexane skeleton. A cis isomer was also prepared along with the trans isomer from a mixture of rac- and meso-bisphosphines. The coordinated boranes were easily removed to afford the corresponding 1,4-diphosphacyclohexanes.