2032-45-3

Basic information

• Product Name: (6Z)-6-[morpholin-4-yl(sulfanyl)methylidene]cyclohexa-2,4-dien-1-one
• CAS NO: 2032-45-3
• Molecular Formula: C₁₁H₁₃NO₂S
• Molecular Weight: 223.2914
• Mol File: 2032-45-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 358°C at 760 mmHg
• Flash Point: 170.3°C
• Density: 1.286g/cm³
• Vapor Pressure: 2.63E-05mmHg at 25°C
• Refractive Index: 1.616
• CAS DataBase Reference: (6Z)-6-[morpholin-4-yl(sulfanyl)methylidene]cyclohexa-2,4-dien-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (6Z)-6-[morpholin-4-yl(sulfanyl)methylidene]cyclohexa-2,4-dien-1-one(2032-45-3)
• EPA Substance Registry System: (6Z)-6-[morpholin-4-yl(sulfanyl)methylidene]cyclohexa-2,4-dien-1-one(2032-45-3)

Safety Data

• Hazardous Substances Data: 2032-45-3(Hazardous Substances Data)

Usage

General Description

The chemical compound "(6Z)-6-[morpholin-4-yl(sulfanyl)methylidene]cyclohexa-2,4-dien-1-one" is a complex organic molecule with a cyclohexadienone backbone and a morpholine-4-yl(sulfanyl)methylidene group attached to it. The "(6Z)" in the name indicates the presence of a specific geometric isomerism. The compound may have potential applications in organic synthesis and medicinal chemistry due to its unique structure and potential reactivity. Further research and investigation are needed to fully understand the properties and potential uses of this chemical compound.

Upstream product

• 110-91-8 morpholine 
• 90-02-8 salicylaldehyde 
• 89-95-2 2-methyl-benzyl alcohol 

Downstream Products

• 96932-65-9 4-[(2-hydroxy-phenyl)-methylsulfanyl-methylene]-morpholinium; iodide 
• 94522-51-7 1-<2-Hydroxy-α-methylmercapto-benzyliden>-morpholiniumbromid 
• 99889-10-8 1-<α-Benzylmercapto-2-hydroxy-benzyliden>-morpholinium-bromid 
• 69-72-7 salicylic acid 

Relevant articles and documents

Sulfated polyborate catalyzed Kindler reaction: a rapid, efficient, and green protocol

A rapid, green, and efficient one-pot, three-component Kindler reaction was developed using a sulfated polyborate catalyst. The method described the reaction of aldehydes, amines/ammonium acetate, and sulfur for the synthesis of thioamides using sulfated polyborate under a solvent free condition at 100?°C. The key features of the present protocol are high yields, short reaction time, easy workup, and recyclability of a catalyst which gives economical as well as ecological rewards. The present method also has an ability to tolerate a variety of functional groups. Graphical abstract: [Figure not available: see fulltext.].

Microwave-assisted rapid hydrolysis and preparation of thioamides by Willgerodt-Kindler reaction

Aldehydes and aryl alkyl ketones were efficiently transformed to thioamides with the same number of carbon atoms via Willgerodt-Kindler reaction under microwave irradiation in solvent-free conditions. The thioamides obtained were hydrolyzed to corresponding carboxylic acids with microwave dielectric heating in one minute. Both reactions are very fast and the yields are excellent.