203626-61-3Relevant articles and documents
Fabrication of a Kagomé-type MOF Membrane by Seeded Growth on Amino-functionalized Porous Al2O3 Substrate
Wang, Xiaoguang,Kusaka, Shinpei,Hori, Akihiro,Matsuda, Ryotaro
, p. 2018 - 2021 (2021)
In this study, we report an efficient fabrication method for the membrane of a metal-organic framework (MOF) (Kgm?OEt) which is one kind of kagomé-type MOF with a two-dimensional (2D) sheet structure having one-dimensional (1D) channels suitable for separ
Linker functionalisation triggers an alternative 3D-topology for Zn-isophthalate-4,4′-bipyridine frameworks
Schneemann, Andreas,Rudolf, Robin,Henke, Sebastian,Takahashi, Yukiko,Banh, Hung,Hante, Inke,Schneider, Christian,Noro, Shin-Ichiro,Fischer, Roland A.
, p. 8198 - 8203 (2017/07/10)
A series of four Zn2+ metal-organic frameworks containing functionalised isophthalate linkers and 4,4′-bipyridine pillars have been prepared and characterised. Isophthalates which contain -OC3H2n+1 alkoxy side chains (with n = 1, 2 or 3) form frameworks with a 3D pillared-layer topology instead of the typical 2D layer topology of the renowned coordination polymers with an interdigitated structure (CIDs), which is found for shorter -OC2H5 side chains. The gas adsorption properties of the materials were analysed using N2, CO2 and O2 adsorption measurements at low temperatures.