20411-04-5

Basic information

• Product Name: (+/-)-Dihydrofumariline-1
• CAS NO: 20411-04-5
• Molecular Weight: 353.375
• Mol File: 20411-04-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-Dihydrofumariline-1(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-Dihydrofumariline-1(20411-04-5)
• EPA Substance Registry System: (+/-)-Dihydrofumariline-1(20411-04-5)

Safety Data

• Hazardous Substances Data: 20411-04-5(Hazardous Substances Data)

Upstream product

• 96838-98-1 C₁₉H₁₅NO₅ 
• 96838-96-9 C₁₉H₁₃NO₅ 
• 96839-00-8 C₁₉H₁₇NO₅ 
• 96860-74-1 Protoberberine 
• 96838-97-0 8,14-Cycloberbine 
• 74-88-4 methyl iodide 
• 96838-99-2 C₂₀H₁₇NO₅ 

Relevant articles and documents

A highly stereoselective synthesis of (±)-dihydrofumariline-1

Stereoselective sodium borohydride reduction of the 8,14-cycloberbine (9) derived from the protoberberine (7), followed by reductive cleavage of C8-N bond of the resulting 13-hydroxy-8, 14-cycloberbine (10) with sodium cyanoborohydride afforded the spirobenzylisoquinoline (12), N-methylation of which via the oxazolidine (13) provided (±)-dihydrofumariline-l (1).