20549-54-6

Basic information

• Product Name: (1R,3R,5R)-1-(3-Hydroxy-4-methylcyclohexyl)ethanone
• Synonyms: (1R,3R,5R)-1-(3-Hydroxy-4-methylcyclohexyl)ethanone
• CAS NO: 20549-54-6
• Molecular Weight: 156.225
• Mol File: 20549-54-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,3R,5R)-1-(3-Hydroxy-4-methylcyclohexyl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3R,5R)-1-(3-Hydroxy-4-methylcyclohexyl)ethanone(20549-54-6)
• EPA Substance Registry System: (1R,3R,5R)-1-(3-Hydroxy-4-methylcyclohexyl)ethanone(20549-54-6)

Safety Data

• Hazardous Substances Data: 20549-54-6(Hazardous Substances Data)

Upstream product

• 619-01-2 (1R,2R,4R)-dihydrocarveol 
• 5524-05-0 (2R,5R)-5-isopropenyl-2-methylcyclohexanone 
• 330798-45-3 (1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane 
• 330798-46-4 (1'R,3'R,4'R)-1-{4'-Methylcyclohexyl-3'-(tert-butyldiphenylsilanyloxy)}ethanone 

Relevant articles and documents

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.