211235-94-8

Basic information

• Product Name: (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol
• Synonyms: (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol
• CAS NO: 211235-94-8
• Molecular Weight: 310.477
• Mol File: 211235-94-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol(211235-94-8)
• EPA Substance Registry System: (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol(211235-94-8)

Safety Data

• Hazardous Substances Data: 211235-94-8(Hazardous Substances Data)

Upstream product

• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 
• 162889-29-4 C₉H₁₇LiO₂ 
• 157886-41-4 (E)-4-iodo-3-methyl-3-buten-1-al, diethylacetal 

Downstream Products

• 116-31-4 vitamin A aldehyde 
• 1209-68-3 3-methyl-5-(2,6,6-trimethylcyclohex-1-enyl)penta-2, 4-dienal 

Relevant articles and documents

Vinyltin acetals in terpenic and nor-terpenic synthesis

Vinyltin acetals obtained by stannylmetallation of homopropargyl acetals with Bu3SnMgMe/CuCN (E configuration) or by titanation of the corresponding alkyltin acetals (Z configuration) have been proved to be efficient storable precursors for the stereoselective synthesis of terpenoids, under mild experimental conditions.Due to the presence of a nucleophilic centre (Csp2-Sn bond) and of a protected electrophilic centre, they are also useful intermediates for an iterative synthesis of retinal and nor-retinoids. - Keywords: vinyltin; acetal; vinyllithium; monoterpenoid; retinal; nor-retinoid