212385-73-4Relevant articles and documents
A Facile Molecular Machine: Optically Triggered Counterion Migration by Charge Transfer of Linear Donor-π-Acceptor Phosphonium Fluorophores
Belyaev, Andrey,Cheng, Yu-Hsuan,Liu, Zong-Ying,Karttunen, Antti J.,Chou, Pi-Tai,Koshevoy, Igor O.
, p. 13456 - 13465 (2019)
The D-π-A type phosphonium salts in which electron acceptor (A=-+PR3) and donor (D=-NPh2) groups are linked by polarizable π-conjugated spacers show intense fluorescence that is classically ascribed to excited-state intramolecular charge transfer (ICT). Unexpectedly, salts with π=-(C6H4)n- and -(C10H6C6H4)- exhibit an unusual dual emission (F1 and F2 bands) in weakly polar or nonpolar solvents. Time-resolved fluorescence studies show a successive temporal evolution from the F1 to F2 emission, which can be rationalized by an ICT-driven counterion migration. Upon optically induced ICT, the counterions move from -+PR3 to -NPh2 and back in the ground state, thus achieving an ion-transfer cycle. Increasing the solvent polarity makes the solvent stabilization dominant, and virtually stops the ion migration. Providing that either D or A has ionic character (by static ion-pair stabilization), the ICT-induced counterion migration should not be uncommon in weakly polar to nonpolar media, thereby providing a facile avenue for mimicking a photoinduced molecular machine-like motion.
Novel organic electroluminescence compounds and organic electroluminescence device containing the same
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Paragraph 0137; 0143-0145, (2020/09/12)
The present invention relates to a novel organic electroluminescent compound and an organic electroluminescent device containing the same. Using the organic electroluminescent compound according to the present invention, it is possible to manufacture an OLED device of lowered driving voltages and advanced power efficiency.
COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF
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Paragraph 0168; 0172-0175, (2020/05/30)
The present invention relates to a novel compound, an organic electric element using the same, and an electronic device thereof. According to the present invention, a luminous efficiency, a color purity and a lifespan of the element can be improved and a driving voltage can be lowered. The organic electric element comprises: an anode; a cathode; and an organic material layer formed between the anode and the cathode.