21369-64-2

Basic information

• Product Name: N-HEXYLLITHIUM
• Synonyms: HEXYLLITHIUM;N-HEXYLLITHIUM;HEXYLLITHIUM SOLUTION, ~2.3 M IN HEXANE;HEXYLLITHIUM, 2.3M SOLUTION IN HEXANE;n-Hexyllithium, 33 wt.% solution in n-hexane;hexyllithium solution;N-HEXYLLITHIUM: 25% IN HEXANE, 1.9M;n-Hexyllithium, 33% (ca 2.47M) soln. in hexane
• CAS NO: 21369-64-2
• Molecular Formula: C₆H₁₃Li
• Molecular Weight: 92.11
• EINECS: 404-950-0
• Product Categories: Alkyl Metals;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Li (Lithium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Organic Bases;Organolithium;Organometallic Reagents;Synthetic Reagents;Alkyl;Chemical Synthesis;Organic Bases;Organometallic Reagents;Synthetic Reagents
• Mol File: 21369-64-2.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 69 °C
• Flash Point: 16 °F
• Appearance: yellow-brown/
• Density: 0.708 g/mL at 25 °C
• Vapor Pressure: 26.9-39.3hPa at 20-35℃
• Storage Temp.: 2-8°C
• Sensitive: Moisture Sensitive
• Stability: Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture a
• BRN: 3600261
• CAS DataBase Reference: N-HEXYLLITHIUM(CAS DataBase Reference)
• NIST Chemistry Reference: N-HEXYLLITHIUM(21369-64-2)
• EPA Substance Registry System: N-HEXYLLITHIUM(21369-64-2)

Safety Data

• Hazard Codes: F,Xn,N,C
• Statements: 11-14/15-17-35-48/20-51/53-62-65-67
• Safety Statements: 26-30-36/37/39-43-45-61-62-16-6
• RIDADR: UN 3394 4.2/PG 1
• WGK Germany: 2
• F: 10-23
• TSCA: Yes
• HazardClass: 4.3
• PackingGroup: I
• Hazardous Substances Data: 21369-64-2(Hazardous Substances Data)

Usage

Chemical Properties

often supplied as a deep yellow solution (ca 2M) in hexane

InChI:InChI=1/C6H13.Li/c1-3-5-6-4-2;/h1,3-6H2,2H3;/rC6H13Li/c1-2-3-4-5-6-7/h2-6H2,1H3

Upstream product

• 111-25-1 1-bromo-hexane 
• 544-10-5 1-Chlorohexane 

Downstream Products

• 111-71-7 heptanal 
• 3429-62-7 trimethylhexylsilane 
• 134340-67-3 N-tosyl-α'-hexyl-α-furfuryl amine 
• 134452-34-9 (R)-N-tosyl-α'-hexyl-α-furfuryl amine 
• 134452-32-7 (S)-N-tosyl-α'-hexyl-α-furfuryl amine 
• 96994-78-4 3-hexyl-phenylthiocyclopentanone 
• 96994-83-1 12β-phenylthio-1-nor-12α-prost-13-ene-11,15-dione 
• 96994-83-1 12α-phenylthio-1-nor-12α-prost-13-ene-11,15-dione 
• 49826-80-4 (2R)-2-Benzyloctane 
• 198956-40-0 (2S)-2-Benzyloctane 
• 1129-69-7 2-hexylpyridine 
• 41446-64-4 trans-6-tetradecene 
• 41446-61-1 cis-6-tetradecene 
• 380371-92-6 n-hexyltriphenylborate potassium salt 

Relevant articles and documents

-

-

Method for producing alkyl-bridged ligand systems and transition metal compounds

The invention relates to a method for producing highly substituted alkyl-bridged ligand systems on the basis of indene derivatives and transition metal compounds. Said alkyl-bridged ligand systems can be obtained in high yields using this method.

Convergent synthesis of alpha -aryl- beta -ketonitriles

The present invention relates to processes for the production of alpha -aryl- beta -ketonitriles, which serve as synthetic intermediates in the preparation of a series of biologically important molecules such as corticotropin releasing factor (CRF) receptor antagonists.