213699-50-4

Basic information

• Product Name: (2S,3S,5S)-3-benzoyloxy-2-cyano-1-methoxycarbonyl-5-methylpyrrolidine
• CAS NO: 213699-50-4
• Molecular Weight: 288.303
• Mol File: 213699-50-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S,5S)-3-benzoyloxy-2-cyano-1-methoxycarbonyl-5-methylpyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,5S)-3-benzoyloxy-2-cyano-1-methoxycarbonyl-5-methylpyrrolidine(213699-50-4)
• EPA Substance Registry System: (2S,3S,5S)-3-benzoyloxy-2-cyano-1-methoxycarbonyl-5-methylpyrrolidine(213699-50-4)

Safety Data

• Hazardous Substances Data: 213699-50-4(Hazardous Substances Data)

Upstream product

• 213699-46-8 (3S,5S)-3-benzoyloxy-5-methyl-2-pyrrolidinone 
• 213699-47-9 (3S,5S)-3-benzoyloxy-1-methoxycarbonyl-5-methyl-2-pyrrolidinone 
• 213699-45-7 (3S,5S)-3-benzoyloxy-1-(tert-butoxycarbonyl)-5-methyl-2-pyrrolidinone 
• 213699-41-3 tert-butyl (2S,4R)-4-((tert-butyldimethylsilyl)oxy)-2-methylpyrrolidine-1-carboxylate 
• 65-85-0 benzoic acid 
• 7677-24-9 trimethylsilyl cyanide 

Downstream Products

• 114882-73-4 (2S,3S,5S)-3-hydroxy-5-methylproline 

Relevant articles and documents

Diastereoselective syntheses of (2R,3R,5R)- and (2S,3S,5S)-3-hydroxy-5- methyl-2-pyrrolidinecarboxylic acid as a component of actinomycin Z1

A novel diastereoselective syntheses of both (2R,3R,5R)-1 and its enantiomer (2S,3S,5S)-1 were accomplished by employing trans-selective nucleophilic addition of cyanide to 3-benzoyloxy-N-acyliminium ions as the key step, starting from trans-4-hydroxy-L-p