21663-52-5Relevant articles and documents
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Burski,J. et al.
, p. 940 - 941 (1978)
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Direct, Microwave-Assisted Synthesis of Isothiocyanates
Janczewski, ?ukasz,Gajda, Anna,Gajda, Tadeusz
supporting information, p. 2528 - 2532 (2019/04/03)
A microwave-assisted desulfuration of readily available dithiocarbamates, formed in situ from primary amines, leading to target isothiocyanates has been developed. This efficient protocol provides a rapid, environmentally benign route to aliphatic and aromatic isothiocyanates.
2,4,4,6-Tetrabromo-2,5-cyclohexadienone as an efficient reagent for phosphine-free electrophilic transformation of alcohols and epoxides
Khajeh-Kolaki, Aslan,Mokhtari, Babak
, p. 251 - 258 (2016/06/01)
In this study, 2,4,4,6-tetrabromo-2,5-cyclohexadienone (TABCO) was prepared and used successfully as a stable phosphine-free reagent for the conversion of alcohols into alkyl thiocyanates and epoxides into 2-hydroxythiocyanates. The reactions seem to proceed via in situ generation of electrophilic sulfur species by reaction of NH4SCN and TABCO. This combined reagent worked well with both alcohols and epoxides in acetonitrile solvent and under solvent-free conditions.