220113-16-6

Basic information

• Product Name: (((3-methylphenyl)amino)carbonyl)ferrocene
• Synonyms: (((3-methylphenyl)amino)carbonyl)ferrocene
• CAS NO: 220113-16-6
• Molecular Weight: 319.186
• Mol File: 220113-16-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (((3-methylphenyl)amino)carbonyl)ferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: (((3-methylphenyl)amino)carbonyl)ferrocene(220113-16-6)
• EPA Substance Registry System: (((3-methylphenyl)amino)carbonyl)ferrocene(220113-16-6)

Safety Data

• Hazardous Substances Data: 220113-16-6(Hazardous Substances Data)

Upstream product

• 1293-79-4 ferrocenoyl chloride 
• 108-44-1 1-amino-3-methylbenzene 

Downstream Products

• 1603897-51-3 4-(3-methylphenyl)-5,6-diphenylferrocene[1,2-c]pyridine-3(4H)-one 

Relevant articles and documents

The effect of protonation on the spectroscopic and redox properties of a series of ferrocenoyl derivatives

Five ferrocenoyl derivatives, containing pyridine (1-4) and benzene (5) moieties, were synthesised and characterised. The effect on the spectroscopic and redox properties of these compounds upon addition of H+ was studied, with NMR studies indicating that protonation took place at the pyridine nitrogens of 1-4. A crystal structure determination of the bis(amide) derivative 4 revealed the presence of two intramolecular hydrogen bonds; these remained intact in solution but were cleaved upon protonation. Protonation induced anodic shifts in the ferrocene-centred redox potential of ferrocene receptors 1, 2 and 4 and also changes in the electronic and NMR spectra of 1-4. A bathochromic shift in the lowest energy spin-allowed d-d band upon protonation was only observed for those compounds which also displayed a pronounced redox response.