22056-06-0Relevant articles and documents
Morita-Baylis-Hillman reaction in eutectic solvent under aqueous medium
Zhao, Sanhu,Zhi, Hangyu,Zhang, Mi,Yan, Qin,Fan, Jianfeng,Guo, Jinchang
, p. 62778 - 62784 (2016)
A series of deep eutectic solvents (DESs) based on choline chloride were prepared and used in the Morita-Baylis-Hillman (M-B-H) reaction. Research showed that the composite solvent (1ChCl/2Gly DES-H2O) is a very effective solvent media for all
Cl-H2O: An efficient and versatile solvent system for the DABCO-catalyzed Morita-Baylis-Hillman reaction
Zhao, Sanhu,He, Meiyan,Guo, Zhaonan,Zhou, Na,Wang, Dou,Li, Jinlong,Zhang, Liwei
, p. 32839 - 32845 (2015/04/27)
An efficient and versatile solvent-catalyst system, [HyEtPy]Cl-H2O-DABCO, has been developed and used in the Morita-Baylis-Hillman reaction. Under the mild reaction conditions, Morita-Baylis-Hillman proceeds very quickly and efficiently. This protocol has notable advantages such as eco-friendliness, ease of work-up and reuse of ionic liquid conveniently, which could help reduce disposal costs and contribute to the development of a new solvent-catalyst system for use in green and continuous chemical processes.
Kinetic resolution of leishmanicidal meta and para (±)-2- [Hydroxy(nitrophenyl)methyl]acrylonitrile catalyzed by CALB: In vitro evaluations of separated meta (R), (S) and (R/S) adducts
Xavier, Francisco J.S.,Neto, José S.S.,Néris, Patrícia L.N.,Oliveira, Marcia R.,Vale, Juliana A.,Vasconcellos, Mario L.A.A.
, p. 7 - 12 (2014/08/05)
The acyl derivatives enantiomers of the Morita-Baylis-Hillman adduct (±)-2-[Hydroxy(m-nitrophenyl)methyl]acrylonitrile (1) and (±)-2-[Hydroxy(p-nitrophenyl)methyl]acrylonitrile (2) were efficiently separated by kinetic resolution catalyzed by lipase B fro
