22099-23-6Relevant articles and documents
A new dibenzothiophene-based dual-channel chemosensor for cyanide with aggregation induced emission
Cui, Yuezhi,Du, Jinhao,Gu, Chuanfeng,Tao, Furong,Zhang, Datong,Zou, Qiqi
, (2021)
Based on dibenzothiophene fluorophore, a new colorimetric and fluorescent sensing material 2-(dibenzothiophenyl-4-ethenylidenyl)-1,3-indanedione (DTI) was developed, which was a favorable turn-off fluorescent sensor of monitoring CN– ion at extremely low detection limit (0.14 μM) in 99 % aq. DMSO solution. The response mechanism of DTI towards CN– could put down to nucleophilic attack of cyanide group (CN–) toward the double-bond between the dibenzothiophene and the 1,3-indanedione units, which breaking intramolecular charge transfer (ICT) process. This mechanism was proposed by 1H NMR, Job's titration and DFT calculation, leading to a significant fluorescence attenuation and a visual color change. The absorption and emission experiments demonstrated that it showed highly sensitive, selective and good stability for CN– in DMSO/H2O (1:99, v/v). Moreover, DTI displayed high effectiveness in monitoring the CN– in test strips achieved to conveniently determinate CN– by naked-eye without any instruments.
Functional material based on stable chemical structure
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Paragraph 0291; 0304; 0306, (2021/08/25)
The invention relates to functional materials based on stable chemical structures. A series of novel donor - acceptor type TADF activated emitters have been designed, which are intended to develop stable OLED. with enhanced operational stability and improved color purity that can be used in full color displays and lighting applications.
Derivative of tetra-substituted pyrrolo [3,2-b] pyrrole and organic electroluminescence device based on same
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Paragraph 0044; 0045, (2017/05/18)
The invention provides a derivative of 2,5-substituted 1,4-di(4-tert-butyl-phenyl) pyrrolo [3,2-b] pyrrole, and application of the derivative. The derivative has the following structural formula as shown in the specification; in the formula, R represents