221045-67-6

Basic information

• Product Name: C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl⁽¹⁺⁾*BF₄^(1-)=[C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl]BF₄
• CAS NO: 221045-67-6
• Molecular Weight: 669.762
• Mol File: 221045-67-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl⁽¹⁺⁾*BF₄^(1-)=[C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl⁽¹⁺⁾*BF₄^(1-)=[C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl]BF₄(221045-67-6)
• EPA Substance Registry System: C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl⁽¹⁺⁾*BF₄^(1-)=[C₅(CH₃)5Rh((C₅H₄N)2C₅H₂N(C₆H₅))Cl]BF₄(221045-67-6)

Safety Data

• Hazardous Substances Data: 221045-67-6(Hazardous Substances Data)

Upstream product

• 13755-29-8 sodium tetrafluoroborate 
• 137540-28-4 [C₅(CH₃)5Rh(C₁₂H₈S)Cl₂] 
• 58345-97-4 4'-phenyl-2,2':6',2-terpyridine 

Relevant articles and documents

Synthesis and characterization of Cp Rh (III) and Ir (III) polypyridyl complexes: Fluxional behaviour of Rh (III) complexes and molecular structure of [Cp*Rh (Ph-terpy)Cl]BF4 complex (Cp=η5- (C5Me5))

Reaction of [Cp*M(μ-Cl)Cl]2 (Cp*=η5- (C5Me5), MRh, Ir) with 4′-phenyl-2,2′: 6′, 2″ terpyridine (Ph-terpy), L 1 and 1,4-bis (2,2′: 6′, 2″-terpyridin-4′-yl)benzene (diterpy), L 2 results in the formation of cationic complexes by the cleavage of halide bridge. These complexes, [Cp*RhL 1Cl]BF4, (1), [ (Cp*RhCl)2L 2] (BF4)2, (2), [Cp*IrL 1Cl]BF4, (3) and [ (Cp*IrCl)2L 2] (BF4)2, (4) are characterised by various spectral methods. Ph-terpy coordinates the metal ion in a bidentate fashion to form mononuclear complexes while diterpy bridges two metal ions to form dinuclear complexes. Complex (1) is crystallographically characterised. In solution Rh (III) complexes show fluxional behavior.