223431-27-4Relevant articles and documents
Aminolysis of aryl ester using tertiary amine as amino donor via c-o and c-n bond activations
Bao, Yong-Sheng,Zhaorigetu, Bao,Agula, Bao,Baiyin, Menghe,Jia, Meilin
, p. 803 - 808 (2014/04/03)
An aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of a broad scope of tertiary amides under neutral and mild conditions. The mechanism may undergo the two key steps of oxidative addition of acyl C-O bond in parent ester and C-N bond cleavage of tertiary amine via an iminium-type intermediate.