22479-32-9

Basic information

• Product Name: Benzenemethanol, 4-chloro-a-methylene-, acetate
• CAS NO: 22479-32-9
• Molecular Formula: C10H9ClO2
• Molecular Weight: 196.633
• Mol File: 22479-32-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-chloro-a-methylene-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-chloro-a-methylene-, acetate(22479-32-9)
• EPA Substance Registry System: Benzenemethanol, 4-chloro-a-methylene-, acetate(22479-32-9)

Safety Data

• Hazardous Substances Data: 22479-32-9(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 99-91-2 para-chloroacetophenone 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 121194-36-3 1-(4-chlorophenyl)-3,3,3-trifluoro-propan-1-one 
• 56157-07-4 (N-methyl-4-methylphenylsulphonylaminomethyl)-(4-chlorophenyl)-ketone 
• 40394-87-4 4-(4-chloro-phenyl)-4-oxo-butyronitrile 
• 1613458-53-9 (E)-1-(4-chlorophenyl)-3,5-diphenylpent-4-en-1-one 
• 1339700-52-5 1-(4'-chlorophenyl)-4,4,4-trifluoro-1-butanone 
• 73402-88-7 2-phenyl-4-(4-chlorophenyl)quinoline 
• 38488-19-6 1-(4-chlorophenyl)-2-(phenylsulfonyl)ethanone 
• 61820-94-8 1-(4-chlorophenyl)-2-tosylethanone 
• 1350844-81-3 3-(4-chlorophenyl)-1-methylisoquinoline 
• 103966-61-6 1-(4-chlorophenyl)ethyl acetate 
• 19759-43-4 (R)-1-(4-chlorophenyl)ethyl acetate 
• 3391-10-4 1-(p-chlorophenyl)ethyl alcohol 
• 99-91-2 para-chloroacetophenone 
• 19759-43-4 (S)-1-(4-chlorophenyl)ethyl acetate 

Relevant articles and documents

Visible-Light-Promoted Synthesis of α-CF2H-Substituted Ketones by Radical Difluoromethylation of Enol Acetates

An efficient and novel visible-light-promoted radical difluoromethylation of enol acetates for the synthesis of α-CF2H-substituted ketones has been described. Upon irradiation under blue LED with catalytic amounts of fac-Ir(ppy)3, this photocatalytic procedure employs difluoromethyltriphenylphosphonium bromide as a radical precursor. Various α-CF2H-substituted ketones are successfully created via designed systems based on the SET process. The methodology has also provided an operationally simple process with broad functional group compatibility.

Formation of δ-Lactones with anti-Baeyer–Villiger Regiochemistry: Investigations into the Mechanism of the Cerium-Catalyzed Aerobic Coupling of β-Oxoesters with Enol Acetates

The cerium-catalyzed, aerobic coupling of β-oxoesters with enol acetates and dioxygen yields δ-lactones with a 1,4-diketone moiety. In contrast to the Baeyer–Villiger oxidation (BVO), where the higher substituted residue migrates; in the case of this oxid

Highly efficient Cu(I)-catalyzed trifluoromethylation of aryl(heteroaryl) enol acetates with CF3 radicals derived from CF3SO 2Na and TBHP at room temperature

An efficient method for the Cu(I)-catalyzed synthesis of α-trifluoromethyl ketones via the addition of CF3 to aryl(heteroaryl) enol acetates by using the readily available CF 3SO2Na (Langlois reagent) has been developed. The reaction is experimentally simple and carried out at room temperature, providing good to excellent yields with wide functional group tolerance.