230953-51-2

Basic information

• Product Name: (VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2⁽²⁺⁾*SO₄^(2-)=[(VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2](SO₄)
• Synonyms: (VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2⁽²⁺⁾*SO₄^(2-)=[(VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2](SO₄)
• CAS NO: 230953-51-2
• Molecular Weight: 955.125
• Mol File: 230953-51-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2⁽²⁺⁾*SO₄^(2-)=[(VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2](SO₄)(CAS DataBase Reference)
• NIST Chemistry Reference: (VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2⁽²⁺⁾*SO₄^(2-)=[(VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2](SO₄)(230953-51-2)
• EPA Substance Registry System: (VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2⁽²⁺⁾*SO₄^(2-)=[(VO)2(Br₂C₆O₄)(C₁₂H₇ClN₂)2](SO₄)(230953-51-2)

Safety Data

• Hazardous Substances Data: 230953-51-2(Hazardous Substances Data)

Upstream product

• 4199-89-7 5-Chloro-1,10-phenanthroline 
• 4370-59-6 bromanilic acid 

Relevant articles and documents

Synthesis, characterization and magnetic properties of binuclear oxovanadium(IV) complexes with a bromanilate bridge

Four novel oxovanadium(IV) binuclear complexes have been synthesized and identified [(VO)2(BA)L2]SO4 [L denotes 2,2'-bipyridine (bpy); 1, 10-phenanthroline (phen); 2,9-dimethyl-1, 10-phenanthroline (Me2-phen) and 5-chloro-1, 10-phenanthroline (Cl-phen), respectively], where BA represents the dianion of bromanilic acid. The complexes were characterized by elemental analyses, molar conductivity and room temperature magnetic moment measurements, IR and electronic spectral studies. Based on these studies, extended BA-bridged structures consisting of two vanadium(IV) ions, each in a square-pyramidal environment, are proposed for these complexes. The complexes [(VO)2(BA)(bpy)2]SO4 (1) and [(VO)2(BA)(phen)2]SO4 (2) were characterized by variable temperature present complexes than that of the complexes [(VO)2(CA)L2]SO4 (L = bpy and phen), so as to increase the antiferromagnetic interaction. This would explain the difference in J values for these complexes.