2315-13-1Relevant articles and documents
Determination of the Absolute Configuration of Chiral Secondary Alcohols from Tetra-O-acetylglucosidation-Induced 1H Nuclear Magnetic Resonance Shifts
Faghih, Ramine,Fontaine, Catherine,Horibe, Isao,Immamura, Paulo M.,Lukacs, Gabor,et al.
, p. 4918 - 4920 (1985)
Tetra-O-acetylglucosidation-induced 1H nuclear magnetic resonance shifts were found highly characteristic of the absolute configuration of representative examples of R and S chiral secondary alcohols.The most important chemical shift changes of structurally diagnostic value for the determination of the absolute configuration of alcohols concern the protons of the aglycone attached to the carbons at β-position relative to the oxygen atom.