23450-27-3

Basic information

• Product Name: Benzene, 1-methoxy-3-(phenylmethyl)-
• CAS NO: 23450-27-3
• Molecular Formula: C14H14O
• Molecular Weight: 198.265
• Mol File: 23450-27-3.mol
• Article Data: 47

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-3-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-3-(phenylmethyl)-(23450-27-3)
• EPA Substance Registry System: Benzene, 1-methoxy-3-(phenylmethyl)-(23450-27-3)

Safety Data

• Hazardous Substances Data: 23450-27-3(Hazardous Substances Data)

Upstream product

• 883-90-9 o-benzyl anisole 
• 6136-67-0 3-methoxybenzophenone 
• 62673-31-8 benzyl(bromo)zinc 
• 105273-30-1 m-methoxyphenyl 2-(1,1,2,2-tetrafluoroethoxy)-1,1,2,2-tetrafluoroethanesulphonate 
• 100-66-3 methoxybenzene 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 98-80-6 phenylboronic acid 
• 3262-89-3 triphenylboroxine 
• 143-66-8 sodium tetraphenyl borate 
• 824-98-6 m-methoxybenzyl chloride 
• 54926-82-8 lithium tributylphenylborate 
• 100-51-6 benzyl alcohol 
• 10507-52-5 benzyl N,N-dimethylcarbamate 
• 10365-98-7 3-methoxyphenylboronic acid 

Downstream Products

• 1383790-49-5 3-benzyl-4-bromophenol 
• 1383790-57-5 3-benzyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 
• 1383790-60-0 ethyl 2-(3-benzyl-4-bromophenoxy)acetate 
• 1383790-67-7 ethyl 2-((2-benzyl-4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-68-8 ethyl 2-((2'-benzyl-4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-69-9 ethyl 2-((2,3'-dibenzyl-4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-70-2 ethyl 2-((2',3-dibenzyl-4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-71-3 ethyl 2-((2,2'-dibenzyl-4'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-77-9 methyl 2-((2-benzyl-4'-(2-(dimethylamino)ethoxy)-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-78-0 methyl 2-((2'-benzyl-4'-(2-(dimethylamino)ethoxy)-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-79-1 methyl 2-((2,3'-dibenzyl-4'-(2-(dimethylamino)ethoxy)-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-80-4 methyl 2-((2',3-dibenzyl-4'-(2-(dimethylamino)ethoxy)-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 1383790-81-5 methyl 2-((2,2'-dibenzyl-4'-(2-(dimethylamino)ethoxy)-[1,1'-biphenyl]-4-yl)oxy)acetate 
• 93434-34-5 (phenyl)(m-methoxyphenyl)methanol acetate 

Relevant articles and documents

Method for reducing carbonyl reduction to methylene under illumination

The invention belongs to the technical field of organic chemical synthesis. The method comprises the following steps: (1) mixing the carbonyl compound and the amine compound in a solvent, reacting 3 - 6 under the illumination of 380 - 456 nm, the reaction system is low in toxicity, high in atom utilization rate 12 - 24h. and production efficiency, safe and controllable in reaction process and capable of simplifying the operation in the preparation and production process. At the same time, the residue toxicity of the reaction is minimized, the pollution caused by the production process to the environment is reduced, and the steps and operations of removing residues after the reaction are simplified. In addition, the reactant feedstock is readily available. The reactant does not need additional modification before the reaction, can be directly used for preparing production, simplifies the operation steps, and shortens the reaction route. The production cost is obviously reduced.

Deoxygenative cross-electrophile coupling of benzyl chloroformates with aryl iodides

This work describes Ni-catalyzed cross-electrophile coupling of benzyl chloroformate derivatives with aryl iodides that generates a wide range of diaryl methane products. The mild reaction conditions merit the C-O bond radical fragmentation of benzyl chloroformates via halide abstraction or a single electron reduction by a Ni catalyst. This work offers a new substrate type for cross-electrophile couplings.

Ni(NIXANTPHOS)-Catalyzed Mono-Arylation of Toluenes with Aryl Chlorides and Bromides

A nickel-catalyzed cross-coupling of toluene derivatives with both aryl bromides and chlorides using a NIXANTPHOS-ligated nickel(II) complex has been developed. The key factor to success is proposed to be the catalyst activation of toluene by a cation-π complex, enabling methyl arenes (pKa ≈ 43) to be deprotonated with the relatively mild base NaN(SiMe3)2. This method facilitates access to a variety of sterically and electronically diverse hetero- and nonheteroaryl-containing diarylmethanes.