2363-84-0

Basic information

• Product Name: 2-Oxohexanal
• Synonyms: 2-Oxohexanal
• CAS NO: 2363-84-0
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.14
• Mol File: 2363-84-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 143°Cat760mmHg
• Flash Point: 41.7°C
• Appearance: /
• Density: 0.935g/cm³
• Vapor Pressure: 5.45mmHg at 25°C
• Refractive Index: 1.407
• CAS DataBase Reference: 2-Oxohexanal(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxohexanal(2363-84-0)
• EPA Substance Registry System: 2-Oxohexanal(2363-84-0)

Safety Data

• Hazardous Substances Data: 2363-84-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H10O2/c1-2-3-4-6(8)5-7/h5H,2-4H2,1H3

Upstream product

• 113093-55-3 1-Benzenesulfonyl-1-diazo-hexan-2-one 
• 693-02-7 hex-1-yne 

Relevant articles and documents

DNA-based asymmetric organometallic catalysis in water

Here, the first examples of DNA-based organometallic catalysis in water that give rise to high enantioselectivities are described. Copper complexes of strongly intercalating ligands were found to enable the asymmetric intramolecular cyclopropanation of α-diazo-β-keto sulfones in water. Up to 84% ee was achieved, in the presence of salmon testes DNA as the only source of chirality, using dipyrido[3,2-a:2′,3′-c]phenazine (dppz) derivatives as ligands.

A NEW FACILE SYNTHESIS OF α-DICARBONYL COMPOUNDS BY OXIDATION OF ALKYNES WITH Mo(VI) PEROXOCOMPLEX PROMOTED BY MERCURIC ACETATE

Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkylalkynes with (HMPA)MoO(O2)2 in 1,2-dichloroethane affords the corresponding α-diketones in good yields.Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing system.