23726-92-3 Usage
Chemical Properties
(Z)-beta-damascone is a colorless to pale yellow liquid with floral, fruity and rose-like aromas, and exists in apple, raspberry oil, etc.
Uses
A food spice that can be used to formulate rose essence.
Synthesis
(Z)-beta-damascone can be synthesized by the reaction of ethyl crocinate and allyl lithium, followed by catalytic isomerization.
Check Digit Verification of cas no
The CAS Registry Mumber 23726-92-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,3,7,2 and 6 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 23726-92:
(7*2)+(6*3)+(5*7)+(4*2)+(3*6)+(2*9)+(1*2)=113
113 % 10 = 3
So 23726-92-3 is a valid CAS Registry Number.
InChI:InChI=1/C13H20O/c1-5-7-11(14)12-10(2)8-6-9-13(12,3)4/h5,7H,6,8-9H2,1-4H3/b7-5-
23726-92-3Relevant articles and documents
A New Synthesis of α- and β-Damascones from the Ionones
Sarandeses, Luis A.,Luche, Jean-Louis
, p. 2757 - 2760 (2007/10/02)
-
Synthesis of (E)-1-Propenyl Ketones from Carboxylic Esters and Carboxamides by Use of Mixed Organolithium-Magnesium Reagents
Fehr, Charles,Galindo, Jose
, p. 228 - 235 (2007/10/02)
The novel reagents formed by combination of allylmagnesium chloride and a strong non-nucleophilic lithium base (LiNR2) convert non- or slowly enolizable carboxylic esters or carboxamides into 2-propenyl ketones which are protected from further reaction by their in situ conversion into enolates.This modified Grignard reaction is applied to efficient syntheses of α-damascone, β-damascone, β-damascenone, and various other (E)-1-propenyl ketones.