24068-29-9Relevant articles and documents
Diarylamine Synthesis via Desulfinylative Smiles Rearrangement
Sephton, Thomas,Large, Jonathan M.,Butterworth, Sam,Greaney, Michael F.
, p. 1132 - 1135 (2022/02/09)
Diarylamines are obtained directly from sulfinamides through a novel rearrangement sequence. The transformation is transition metal-free and proceeds under mild conditions, providing facile access to highly sterically hindered diarylamines that are otherw
Solvent- and ligand-free palladium-catalyzed amination of aryl halides
Basolo, Luca,Bernasconi, Alice,Broggini, Gianluigi,Gazzola, Silvia,Beccalli, Egle M.
, p. 3151 - 3156 (2013/12/04)
An environmentally friendly and economically favorable approach to the formation of C-N bonds is presented. The methodology is particularly interesting in that the reaction is realized under both solvent- and ligand-free conditions and involves the use of
Optimised conditions for styrene syntheses using Suzuki-Miyaura couplings and catalyst-ligand-base pre-mixes
Henderson, Laura,Knight, David W.,Rutkowski, Piotr,Williams, Andrew C.
experimental part, p. 4654 - 4656 (2012/09/05)
Optimised conditions are reported for Suzuki-Miyaura couplings between N-tosyl-2-bromo-benzylamines and -phenethylamines with vinylboronic acids, using pre-mixes of catalyst, ligand and base, leading to the corresponding 2-tosylaminomethyl- and 2-tosylami