24176-50-9Relevant articles and documents
Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts
Askari, Mohammad S.,Effaty, Farshid,Gennarini, Federica,Orio, Maylis,Le Poul, Nicolas,Ottenwaelder, Xavier
supporting information, p. 8678 - 8689 (2020/03/04)
A series of copper/nitrosoarene complexes was created that mimics several steps in biomimetic O2 activation by copper(I). The reaction of the copper(I) complex of N,N,N′,N′-tetramethypropylenediamine with a series of para-substituted nitrosobenzene deriva
Cross-dimerization of nitrosobenzenes in solution and in solid state
Halasz, Ivan,Biljan, Ivana,Novak, Predrag,Me?trovi?, Ernest,Plavec, Janez,Mali, Gregor,Smre?ki, Vilko,Van?ik, Hrvoj
experimental part, p. 19 - 25 (2009/05/08)
Cross-linking of nitrosobenzenes to heterodimers (azodioxides) when they are not sterically crowded with large groups in ortho-position was studied by NMR and FT-IR spectroscopy, X-ray crystallography as well as by cryogenic photolysis. It was found for the first time that cross-linked dimers (heterodimers) exist both in solution and in solid state and that they appear in the crystal together with homodimers. The system is used as a model for studying organic solid solution formation. The role of molecular packing in formation of a weak chemical bond is also discussed.