24341-81-9

Basic information

• Product Name: 2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
• Synonyms: 2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
• CAS NO: 24341-81-9
• Molecular Weight: 244.104
• Mol File: 24341-81-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine(24341-81-9)
• EPA Substance Registry System: 2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine(24341-81-9)

Safety Data

• Hazardous Substances Data: 24341-81-9(Hazardous Substances Data)

Upstream product

• 873-51-8 phenylborondichloride 
• 71-43-2 benzene 
• 3262-89-3 triphenylboroxine 
• 591-50-4 iodobenzene 
• 960-71-4 triphenylborane 
• 100123-15-7 chloro-phenoxy-phenyl-borane 
• 108-86-1 bromobenzene 
• 5656-71-3 2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 479-27-6 naphthalene-1,8-diamine 
• 98-80-6 phenylboronic acid 
• 1483-72-3 diphenyliodonium chloride 
• 1214264-88-6 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 14190-17-1 diphenyliodonium acetate 
• 28249-75-4 2-phenyl-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one 

Downstream Products

• 479-27-6 naphthalene-1,8-diamine 
• 98-80-6 phenylboronic acid 
• 60548-84-7 1,8-naphthylene phenylboronate 
• 613-37-6 4-methoxylbiphenyl 
• 86-26-0 2-methoxy-1,1'-biphenyl 
• 2113-56-6 3-methoxybiphenyl 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 644-08-6 4-Methylbiphenyl 

Relevant articles and documents

Solution-state 15N NMR and solid-state single-crystal XRD study of heterosubstituted diazaboroles and borinines prepared via an effective and simple microwave-assisted solvent-free synthesis

A quick and simple, solvent-free synthesis of nitrogen-basedboroles and borinines derived from 1,2-diaminobenzene and 1,8-diaminonaphthalene is reported and compared with the traditional synthetic method. Characterization by 15N NMR spectroscop

Diazaboryl-naphthyl-ketone: A New Scaffold with Bright Fluorescence, Aggregation-Induced Emission, and Application in the Quantitation of Trace Boronic Acids in Drug Intermediates

This study describes the synthesis, structure, and photophysical properties of a new luminescent polyaromatic boronic acid scaffold, diazaboryl-naphthyl-ketones (DNKs). These stable compounds display extremely bright fluorescence, aggregation-induced emis

Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H-B(dan) as a B(dan) electrophile

H-B(dan) was demonstrated to serve as a B(dan) electrophile, despite its highly diminished boron-Lewis acidity, leading to direct and transition metal-free approach to R-B(dan) of high synthetic utility upon treatment with Grignard reagents. Iterative cross-coupling of 5-bromo-2-pyridyl-B(dan), synthesized by the present method, was also achieved.

Bench-Stable Sulfoxide-Based Boronates: Preparation and Application in a Tandem Suzuki Reaction

A set of novel aromatic and heteroaromatic bench-stable sulfoxide-based boronates was prepared. The structure of the boronates was established by means of X-ray crystallography, and the prepared boronates were successively used in Suzuki cross-coupling reactions under different conditions. We also developed a tandem Suzuki reaction so that a base is generated during the nucleophilic addition of Grignard reagents to 4-bromobenzaldehyde. The formed intermediates were smoothly coupled with the prepared boronates and the boronic acids under external base-free conditions. (Figure presented.).