24556-94-3

Basic information

• Product Name: 3-Methylbenzo[d]thiazol-3-iuM broMide
• Synonyms: 3-Methylbenzo[d]thiazol-3-iuM broMide
• CAS NO: 24556-94-3
• Molecular Formula: C8H8BrNS
• Molecular Weight: 230.12482
• Mol File: 24556-94-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Methylbenzo[d]thiazol-3-iuM broMide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methylbenzo[d]thiazol-3-iuM broMide(24556-94-3)
• EPA Substance Registry System: 3-Methylbenzo[d]thiazol-3-iuM broMide(24556-94-3)

Safety Data

• Hazardous Substances Data: 24556-94-3(Hazardous Substances Data)

Upstream product

• 95-16-9 1,3-Benzothiazole 
• 74-83-9 methyl bromide 

Relevant articles and documents

THE CHELETROPIC FRAGMENTATION OF HYPERVALENT THREE-MEMBERED THIAHETEROCYCLIC INTERMEDIATES

Lithio-imidazolium salts 10, generated in-situ from N'N-dimethylimidazolium salts 9, readily undergo sulfonylation with sulfur dioxide, sulfines, N-sulfinylamines, and thiirane.The resulting zwitterionic species 4 fragment thermally to yield the corresponding imidazolium thione 5 with the hypervalent three-membered thiaheterocyclic intermediates 3 connecting 4 and 5 on the reaction surface.The non-linear cheletropic fragmentation of these relatively stable hypervalent sulfuranes appears to be general for this class of compounds (3 or 4), and the experimental results are in accord with theoretical considerations.