247043-59-0

Basic information

• Product Name: C₁₁H₁₁NO₂
• Synonyms: C₁₁H₁₁NO₂
• CAS NO: 247043-59-0
• Molecular Weight: 189.214
• Mol File: 247043-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₁NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₁NO₂(247043-59-0)
• EPA Substance Registry System: C₁₁H₁₁NO₂(247043-59-0)

Safety Data

• Hazardous Substances Data: 247043-59-0(Hazardous Substances Data)

Upstream product

• 55-21-0 benzamide 
• 10487-71-5 crotonyl chloride 

Downstream Products

• 1136090-60-2 C₁₈H₁₇N₅O₂ 
• 1233762-22-5 C₁₈H₂₀N₂O₃ 

Relevant articles and documents

Photoredox-Controlled β-Regioselective Radical Hydroboration of Activated Alkenes with NHC-Boranes

In this Communication, we report an unprecedented β-regioselective radical inverse hydroboration (compared with ionic hydroboration) of α,β-unsaturated amides with NHC-BH3 enabled by photoredox catalysis. Density functional theory (DFT) calculations show that the unique photoredox cycle is a key factor to control the β-regioselective radical hydroboration, by lowering the energy barrier in comparison with other pathways. This protocol provides a general and convenient route to construct a wide range of structurally diverse β-borylated amides in synthetically useful yields under mild conditions.