24724-18-3

Basic information

• Product Name: 10,11-Dibromoundecane-1-ol
• Synonyms: 10,11-Dibromo-1-undecanol;10,11-Dibromoundecane-1-ol
• CAS NO: 24724-18-3
• Molecular Formula: C₁₁H₂₂Br₂O
• Molecular Weight: 330.1
• Mol File: 24724-18-3.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 355.1°C at 760 mmHg
• Flash Point: 168.5°C
• Appearance: /
• Density: 1.408g/cm³
• Vapor Pressure: 1.83E-06mmHg at 25°C
• Refractive Index: 1.508
• PKA: 15.20±0.10(Predicted)
• CAS DataBase Reference: 10,11-Dibromoundecane-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 10,11-Dibromoundecane-1-ol(24724-18-3)
• EPA Substance Registry System: 10,11-Dibromoundecane-1-ol(24724-18-3)

Safety Data

• Hazardous Substances Data: 24724-18-3(Hazardous Substances Data)

Usage

Physical state

White to light yellow solid

Molecular weight

327.11 g/mol

Usage

Organic synthesis, chemical research, pharmaceuticals, and specialty chemicals production

Purity

High purity

Role

Building block in the synthesis of various organic compounds

InChI:InChI=1/C11H22Br2O/c12-10-11(13)8-6-4-2-1-3-5-7-9-14/h11,14H,1-10H2

Upstream product

• 2774-84-7 undec-10-yn-1-ol 
• 6308-96-9 10,11-dibromo-undecanoic acid 
• 112-43-6 10-Undecen-1-ol 
• 111-81-9 Methyl 10-undecenoate 

Downstream Products

• 103-30-0 (E)-1,2-diphenyl-ethene 
• 112-43-6 10-Undecen-1-ol 
• 1002-94-4 (10Z,12E)-hexadecadien-1-ol 
• 765-17-3 (10E,12Z)-hexadeca-10,12-dien-1-ol 
• 71317-67-4 15-Chloro-(Z,Z)-3,5-pentadecadiene 
• 73264-89-8 (Z₁₁,E₁₃)-11,13-Hexadecadienal 
• 71317-73-2 (11Z,13Z)-11,13-hexadecadienal 
• 5227-24-7 12-((2R,6S)-5-Hydroxy-6-methyl-piperidin-2-yl)-dodecan-2-one 
• 5227-24-7 3 β epi-3 cassine 
• 86252-74-6 (2E,13Z)-octadeca-2,13-dienyl acetate 
• 123551-47-3 (2E,13Z)-2,13-octadecadien-1-ol 
• 71317-72-1 undec-10-yn-1-yl bromide 
• 2774-84-7 undec-10-yn-1-ol 

Relevant articles and documents

Merging shuttle reactions and paired electrolysis for reversible vicinal dihalogenations

Vicinal dibromides and dichlorides are important commodity chemicals and indispensable synthetic intermediates in modern chemistry that are traditionally synthesized using hazardous elemental chlorine and bromine. Meanwhile, the environmental persistence of halogenated pollutants necessitates improved approaches to accelerate their remediation. Here, we introduce an electrochemically assisted shuttle (e-shuttle) paradigm for the facile and scalable interconversion of alkenes and vicinal dihalides, a class of reactions that can be used both to synthesize useful dihalogenated molecules from simple alkenes and to recycle waste material through retro-dihalogenation. The reaction is demonstrated using 1,2-dibromoethane, as well as 1,1,1,2-tetrachloroethane or 1,2-dichloroethane, to dibrominate or dichlorinate, respectively, a wide range of alkenes in a simple setup with inexpensive graphite electrodes. Conversely, the hexachlorinated persistent pollutant lindane could be fully dechlorinated to benzene in soil samples using simple alkene acceptors.

Synthesis of (3Z,13Z)-3,13-octadecadienyl acetate - Sex pheromone of Synanthedon tenuis-using readily available C11-synthon

Synthesis of (3Z,13Z)-3,13-octadecadienyl acetate has been achieved from the readily available 10-undecen-1-ol using cheaper reagents and less number of steps. In the key step alkylation of an alkyne is performed with solid sodamide giving the product in 50% yield. The method can be easily scaled-up.

Convenient methods for the reduction of amides, nitriles, carboxylic esters, acids and hydroboration of alkenes using NaBH4/I2system

Reaction of amides with NaBH4-I2 system in THF gives the corresponding amines in 70-76% yields. Reduction of nitriles yields the corresponding amines in 70-75% yields. The I2/NaBH4 system is useful in the hydrocarboration of olefins and the corresponding alcohols are obtained in 78-92% yields after H2O2/OH- oxidation. The reagent system is also useful for the reduction of carboxylic esters and acids to the corresponding alcohols in 60-90% yields.