24766-10-7

Basic information

• Product Name: diethyl 2-n-butylsuccinate
• Synonyms: diethyl 2-n-butylsuccinate
• CAS NO: 24766-10-7
• Molecular Weight: 230.304
• Mol File: 24766-10-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diethyl 2-n-butylsuccinate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2-n-butylsuccinate(24766-10-7)
• EPA Substance Registry System: diethyl 2-n-butylsuccinate(24766-10-7)

Safety Data

• Hazardous Substances Data: 24766-10-7(Hazardous Substances Data)

Upstream product

• 623-91-6 diethyl Fumarate 
• 13049-86-0 diethyl 2-(ethoxycarbonylmethylene)malonate 
• 141-05-9 Diethyl maleate 

Relevant articles and documents

Reduction-alkylation with organocopper(I) reagents-alkyl halydes: Highly regioselective α-alkylation of γ-acetoxy-α,β-enoates with lithium dibutylcuprate-alkyl halides and difference in the reactivity of electron-deficient olefins with organocopper(I)-Lewis acid reagents

Reaction of γ-acetoxy-α,β-enoates with lithium dialkylcuprate followed by alkyl halides results in the predominant or exclusive formation of α-alkyl-β,γ-enoates in high yields under mild conditions, and a synthetic application to (+-)-α-vetispirene is presented.Treatment of diethyl fumarate and triethoxycarbonylethylene with Bu2CuLi*AlCl3 led to 1,4-addition to give conjugate adducts in high yields.In sharp contrast, diethyl maleate and tetraethoxycarbonylethylene predominantly gave the respective reduction products.Evidence for a presumed dianionic intermediate, based on trapping with some electrophyles, is also presented.Keywords - γ-oxygenated α,β-enoate; β,γ-enoate; deconjugative reduction; α-vetispirene; lithium dialkylcuprate; organocopper(I)-Lewis acid.