25083-95-8

Basic information

• Product Name: 2-Propanone, 1-bromo-1-(3,4-dimethoxyphenyl)-
• CAS NO: 25083-95-8
• Molecular Formula: C11H13BrO3
• Molecular Weight: 273.126
• Mol File: 25083-95-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Propanone, 1-bromo-1-(3,4-dimethoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-bromo-1-(3,4-dimethoxyphenyl)-(25083-95-8)
• EPA Substance Registry System: 2-Propanone, 1-bromo-1-(3,4-dimethoxyphenyl)-(25083-95-8)

Safety Data

• Hazardous Substances Data: 25083-95-8(Hazardous Substances Data)

Upstream product

• 776-99-8 3,4-dimethoxyphenylacetone 
• 60-29-7 diethyl ether 
• 7726-95-6 bromine 
• 67-66-3 chloroform 
• 94-36-0 dibenzoyl peroxide 
• 93-16-3 Methylisoeugenol 

Downstream Products

• 95316-29-3 2-Hydroxy-1-<2-methoxy-phenoxy>-1-<3,4-dimethoxy-phenyl>-propan 
• 86370-54-9 1-ethoxy-1-(3,4-dimethoxy-phenyl)-acetone 
• 101268-66-0 2-ethoxy-1-(3,4-dimethoxy-phenyl)-propan-1-one 
• 38007-20-4 1-acetoxy-1-(3,4-dimethoxy-phenyl)-acetone 
• 71367-49-2 1-(3,4-dimethoxyphenyl)propane-1,2-dione 
• 102119-64-2 1-(3,4-Dimethoxy-phenyl)-3-furan-2-yl-propan-2-one 
• 37803-43-3 1-<2-Methoxy-phenoxy>-1-<3.4-dimethoxy-phenyl>-propanon-(2) 
• 102137-00-8 2-(3',4'-dimethoxyphenyl)-8-oxabicyclo<3.2.1>oct-6-en-3-one 
• 102137-00-8 2-(3',4'-dimethoxyphenyl)-8-oxabicyclo<3.2.1>oct-6-en-3-one 
• 100059-85-6 1-(3,4-dimethoxy-phenyl)-2-oxo-propane-1-sulfonic acid 
• 13419-49-3 1-(3,4-dimethoxyphenyl)-1-hydroxy-propan-2-one 

Relevant articles and documents

SYNTHESIS AND REACTIONS OF 2-ARYL-8-OXABICYCLOOCT-6-EN-3-ONES

A number of 1-aryl-1-bromopropanones have been prepared and converted into the corresponding oxyallyl carbocations.These were reacted with furan to produce the expected 2-aryl-8-oxabicyclooct-6-en-3-ones, as well as a number of interesting side-products.These included 3-aryl-propanoic acid esters produced via Favorskii rearrangements.Attempts to cleave the ether linkage in the cycloadducts using bromotrimethylsilane produced instead 1-aryl-3-furylpropanones in excellent yield.