25091-25-2

Basic information

• Product Name: (3E)-3-Dodecene-1-yne
• Synonyms: (3E)-3-Dodecene-1-yne;(E)-3-Dodecen-1-yne
• CAS NO: 25091-25-2
• Molecular Formula: C₁₂H₂₀
• Molecular Weight: 164.29
• Mol File: 25091-25-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3E)-3-Dodecene-1-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (3E)-3-Dodecene-1-yne(25091-25-2)
• EPA Substance Registry System: (3E)-3-Dodecene-1-yne(25091-25-2)

Safety Data

• Hazardous Substances Data: 25091-25-2(Hazardous Substances Data)

Upstream product

• 74646-36-9 Dodeca-1-yn-4-ol 
• 78808-41-0 dodeca-1,2-dien-4-ol 
• 764-93-2 1-decyne 
• 156-60-5 trans-1,2-dichloroethylene 
• 205811-72-9 ((E)-Dodec-3-en-1-ynyl)-trimethyl-silane 
• 66291-52-9 (E)-1-iododec-1-ene 
• 66553-46-6 (1E)-1-iodododec-1-ene 
• 4301-14-8 acetylenemagnesium bromide 
• 629-05-0 n-octyne 
• 84751-14-4 (E)-dec-3-en-1-yn-1-yltrimethylsilane 

Downstream Products

• 911001-69-9 [((E)-Dodec-3-en-1-ynyl)oxy]-triisopropyl-silane 

Relevant articles and documents

Dialkylaluminum hydride-promoted cyclodimerization of silylated 1,3-enynes via skeletal rearrangement

The dialkylaluminum hydride-promoted reaction of 1-silylalk-3-en-1-ynes gave symmetrical 1,2,3,5-tetrasubstituted benzenes as single regioisomers. The novel cyclodimerization via skeletal rearrangement can be rationalized by an unprecedented mechanism inv

Silver-catalyzed hydroamination of siloxy alkynes

(Chemical Equation Presented) New catalytic process: The silver-catalyzed hydroamination of siloxy alkynes with secondary amides furnishes silyl ketene aminals with high efficiency and excellent diastereoselectivity (see scheme), including some that are unavailable by conventional silylation methods. The reaction comprises a fast and reversible silver-alkyne complexation, followed by a rate-determining C-N bond-forming step.