25116-07-8

Basic information

• Product Name: N-[3-(2,2-dimethylpropionylamino)-2-methylphenyl]-2,2-dimethylpropionamide
• Synonyms: N-[3-(2,2-dimethylpropionylamino)-2-methylphenyl]-2,2-dimethylpropionamide
• CAS NO: 25116-07-8
• Molecular Weight: 290.406
• Mol File: 25116-07-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-[3-(2,2-dimethylpropionylamino)-2-methylphenyl]-2,2-dimethylpropionamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[3-(2,2-dimethylpropionylamino)-2-methylphenyl]-2,2-dimethylpropionamide(25116-07-8)
• EPA Substance Registry System: N-[3-(2,2-dimethylpropionylamino)-2-methylphenyl]-2,2-dimethylpropionamide(25116-07-8)

Safety Data

• Hazardous Substances Data: 25116-07-8(Hazardous Substances Data)

Upstream product

• 823-40-5 2,6-toluenediamine 
• 407-25-0 trifluoroacetic anhydride 
• 606-20-2 2,6-dinitrotoluene 
• 3282-30-2 pivaloyl chloride 

Downstream Products

• 179810-47-0 2,6-bis(2,2-dimethylpropionylamino)benzoic acid 

Relevant articles and documents

Contribution of intramolecular NH...O hydrogen bonds to magnesium-carboxylate bonds

A series of magnesium carboxylate complexes containing intramolecular NH...O hydrogen bonds were synthesized. Their molecular structures were determined by X-ray analysis. A direct NH...O hydrogen bond to the coordinated oxygen atom elongated the Mg-O bond, while a hydrogen bond to the carbonyl group shortened the Mg-O bond. Double NH...O hydrogen bonds significantly lowered the basicity of the carboxylate anion and prevented coordination to the Mg ion in a trans configuration; however, a cis-dicarboxylate complex was successfully obtained. Strong coordination of water to the Mg2+ ion stabilizes the weak Mg-carboxylate bond at the trans position. In contrast, a weak Mg-carboxylate bond strengthens the Mg-O(water) bond, probably increasing the acidity. Based on the experimental results and theoretical calculations, a new switching mechanism is proposed. In the proposed mechanism, the acidity of the coordinated water on magnesium is controlled during catalytic hydrolysis in endonuclease.

Meta-bis anilide derivatives and their utility as herbicides

Compounds corresponding to the formula: SPC1 In which R1 and R2 are, independently, hydrogen, alkyl, alkoxyalkyl, cycloalkyl, pinonyl, ethylcycloalkyl, lower alkenyl, halogenated lower alkyl, benzyl, ethylphenyl, 2,4-dichlorophenoxy-methylene, styryl, furyl, phenyl or substituted phenyl in which the substituents are nitro, halogen, methyl, or methoxy; R3 and R4 are, independently, hydrogen or lower alkyl; X and Y are independently oxygen or sulfur; and Z is halogen, nitro, amino, lower alkyl, lower alkoxy or trifluoromethyl and n is an integer having a value from 0 to 4. The above compounds are effective herbicides, particularly for the control of grasses and broadleaf plants with both pre-emergence and post-emergence activity. Representative compounds are: m-propionamidobutyranilide, m-bis-2,2-dimethylvaleranilide, m-isobutyramido trichloroacetanilide, m-isobutyramido-2-ethylbutyranilide, m-t-butylacetamidopropionanilide, and 3'-N-ethyl propionamido-propionalide. This application is a continuation of application Ser. No. 180,916, filed Sept. 15, 1971, which is a continuation of application Ser. No. 20,104, filed Mar. 16, 1970, which is a continuation-in-part of application Ser. No. 741,267, filed July 1, 1968, which is a continuation-in-part of application Ser. No. 659,865, filed Aug. 11, 1967, all now abandoned.