25118-59-6

Basic information

• Product Name: 4-BROMO-3-CHLOROBENZOIC ACID
• Synonyms: 3-chloro-4-Bromor-benzoic acid
• CAS NO: 25118-59-6
• Molecular Formula: C₇H₄BrClO₂
• Molecular Weight: 235.47
• Product Categories: C7;Carbonyl Compounds;Carboxylic Acids;intermediate
• Mol File: 25118-59-6.mol
• Article Data: 6

Chemical Properties

• Melting Point: 220-224 °C
• Boiling Point: 333.686 °C at 760 mmHg
• Flash Point: 155.608 °C
• Appearance: /
• Density: 1.809±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 5.32E-05mmHg at 25°C
• Refractive Index: 1.621
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: soluble in Methanol
• PKA: 3.60±0.10(Predicted)
• CAS DataBase Reference: 4-BROMO-3-CHLOROBENZOIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMO-3-CHLOROBENZOIC ACID(25118-59-6)
• EPA Substance Registry System: 4-BROMO-3-CHLOROBENZOIC ACID(25118-59-6)

Safety Data

• Hazard Codes: Xn,N,Xi
• Statements: 22-50/53
• Safety Statements: 60-61
• RIDADR: UN 2811 6.1/PG 3
• WGK Germany: 3
• HazardClass: IRRITANT
• PackingGroup: Ⅲ
• Hazardous Substances Data: 25118-59-6(Hazardous Substances Data)

Usage

Chemical Properties

White solid

InChI:InChI=1/C7H4BrClO2/c8-5-2-1-4(7(10)11)3-6(5)9/h1-3H,(H,10,11)

Upstream product

• 6627-51-6 1-bromo-2-chloro-4-methylbenzene 
• 535-80-8 3-chlorobenzoate 
• 163596-75-6 4-bromo-3-nitrobenzaldehyde 
• 117738-74-6 methyl 4-bromo-3-chlorobenzoate 
• 586-76-5 4-Bromobenzoic acid 
• 615-65-6 2-chloro-4-methyl-benzenamine 
• 106-38-7 para-bromotoluene 
• 108-41-8 1-chloro-3-methylbenzene 
• 1122-91-4 4-bromo-benzaldehyde 
• 120077-69-2 3-chloro4-bromo-benzaldehyde 

Downstream Products

• 21900-32-3 4-bromo-3-chlorobenzoyl chloride 
• 625446-26-6 4-Bromo-2-chloro-thiobenzoic acid S-pyridin-2-yl ester 
• 570407-88-4 tert-butyl 3-chloro-4-fluorobenzoate 
• 1235711-34-8 4-bromo-3-chloro-N-methoxy-N-methyl-benzamide 
• 54256-44-9 4-n-butyl-3-chlorobenzoyl chloride 
• 1608148-02-2 3-(3-iodo-4-isopropoxyphenyl)-5-(4-n-butyl-3-chlorophenyl)-1,2,4-oxadiazole 
• 1608148-00-0 4-n-butyl-3-chlorobenzoic acid 
• 1608147-96-1 methyl 4-n-butyl-3-chlorobenzoate 
• 1608147-98-3 n-butyl 4-n-butyl-3-chlorobenzoate 
• 117738-74-6 methyl 4-bromo-3-chlorobenzoate 
• 1610372-97-8 3-chloro-N,N-dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide 
• 1369900-22-0 4-bromo-3-chloro-N,N-dimethylbenzamide 

Relevant articles and documents

Method for preparing normal 2-docodone intermediate (I)-(C)-( -4- C)-(C -5-) bromo-(M-chlorobenzoic acid) (by machine translation)

The method sequentially comprises the following steps: a new, synthetic, route and a selective. reduction 2 - reaction are supplied to the preparation method of the anti.coccidiosis intermediate, and: the method sequentially comprises the following, steps

DMSO/I2 mediated C-C bond cleavage of α-ketoaldehydes followed by C-O bond formation: A metal-free approach for one-pot esterification

A novel and efficient I2/DMSO mediated metal-free strategy is presented for the direct C-C bond cleavage of aryl-/heteroaryl- or aliphatic α-ketoaldehydes by C2-decarbonylation and C1-carbonyl oxidation to give the corresponding carboxylic acids followed by esterification in one pot, offering excellent yields in both the steps. Here, DMSO acts as the oxygen source/oxidant and this reaction works very well under both conventional heating and microwave irradiation. This is a very simple and convenient protocol.

Pesticidal compounds

Bicyclooctane pesticides of the formula are prepared by cyclisation of In these formulae R may be various organic groups and is preferably n-butyl or n-propyl while R2 is a polysubstituted phenyl group.