251984-08-4Relevant articles and documents
[Am(C5Me4H)3]: An Organometallic Americium Complex
Goodwin, Conrad A. P.,Su, Jing,Albrecht-Schmitt, Thomas E.,Blake, Anastasia V.,Batista, Enrique R.,Daly, Scott R.,Dehnen, Stefanie,Evans, William J.,Gaunt, Andrew J.,Kozimor, Stosh A.,Lichtenberger, Niels,Scott, Brian L.,Yang, Ping
supporting information, p. 11695 - 11699 (2019/08/01)
We report the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1H NMR solution spectroscopy /solid-state UV/Vis-nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am3+ organometallic complex, [Am(C5Me4H)3] (1). This constitutes the first quantitative data on Am?C bonding in a molecular species.
Synthesis, structure, and 15N NMR studies of paramagnetic lanthanide complexes obtained by reduction of dinitrogen
Evans, William J.,Rego, Daniel B.,Ziller, Joseph W.
, p. 10790 - 10798 (2008/10/09)
The recently discovered LnZ3/M and LnZ2Z′/M methods of reduction (Ln = lanthanide; M = alkali metal; Z, Z′ = monoanionic ligands that allow these combinantions to generate "LnZ 2" reactivity) have been applied to provide t