253151-64-3

Basic information

• Product Name: (benzylisopropyldithiocarbamate)NiI(triphenylphosphine)
• CAS NO: 253151-64-3
• Molecular Weight: 672.256
• Mol File: 253151-64-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (benzylisopropyldithiocarbamate)NiI(triphenylphosphine)(CAS DataBase Reference)
• NIST Chemistry Reference: (benzylisopropyldithiocarbamate)NiI(triphenylphosphine)(253151-64-3)
• EPA Substance Registry System: (benzylisopropyldithiocarbamate)NiI(triphenylphosphine)(253151-64-3)

Safety Data

• Hazardous Substances Data: 253151-64-3(Hazardous Substances Data)

Upstream product

• 787624-20-8 bis(triphenylphosphine)nickel(II) diiodide 
• 82421-76-9 (benzylisopropyldithiocarbamate)2 nickel(II) 

Relevant articles and documents

Benzylisopropyldithiocarbamate complexes of nickel with triphenylphosphine in the coordination sphere

Nickel(II) benzylisopropyldithiocarbamate complexes of the composition [Ni(bziPrdtc)2], [NiCl(bziPrdtc)(PPh3)]·CHCl3 and [NiX(bziPrdtc)(PPh3)] (X=Cl, Br, I, NCS; bz=C7H7, iPr=C3H7, dtc=S2CN-, PPh3=triphenylphosphine) have been synthesized. The complexes have been characterized by elemental analyses, IR and electronic spectroscopies, thermal analysis, magnetochemical and conductivity measurements. A single crystal X-ray analysis of the [NiCl(bziPrdtc)(PPh3)]·CHCl3, [NiBr(bziPrdtc)(PPh3)] and [NiI(bziPrdtc)(PPh3)] confirms four-coordinated nickel in a distorted square-planar arrangement with the NiS2PX chromophore. Elsevier Science Ltd.