2532-06-1

Basic information

• Product Name: Benzenesulfonamide, N-methyl-N-(phenylsulfonyl)-
• CAS NO: 2532-06-1
• Molecular Formula: C13H13NO4S2
• Molecular Weight: 311.383
• Mol File: 2532-06-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-methyl-N-(phenylsulfonyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-methyl-N-(phenylsulfonyl)-(2532-06-1)
• EPA Substance Registry System: Benzenesulfonamide, N-methyl-N-(phenylsulfonyl)-(2532-06-1)

Safety Data

• Hazardous Substances Data: 2532-06-1(Hazardous Substances Data)

Upstream product

• 98-09-9 benzenesulfonyl chloride 
• 74-89-5 methylamine 
• 20734-58-1 N,N,N',N'-tetramethyl-1,8-diaminonaphthalene 
• 139198-75-7 [bis(diphenylphosphino)ferrocene(Pd(CH₃)Cl)] 
• 133745-75-2 N-fluorobis(benzenesulfon)imide 
• 211935-49-8 Me₂Pd(dppf) 
• 2618-96-4 dibenzenesulfonamide 
• 74-88-4 methyl iodide 

Downstream Products

• 825-55-8 2-phenylthiophene 
• 605-02-7 1-phenylnaphthalene 
• 2920-38-9 4-cyano-1,1'-biphenyl 
• 92-91-1 biphenyl-4-acetaldehyde 
• 644-08-6 4-Methylbiphenyl 
• 92-52-4 biphenyl 
• 613-37-6 4-methoxylbiphenyl 
• 5183-78-8 methyl(phenylsulfonyl)amide 

Relevant articles and documents

Polysulfonylamines, LXXVI [1]: Occurrence of two supramolecular isomers in one crystal: Synthesis and structure of the monomeric 18-crown-6 complex (CH2CH2O)6·2 MeN(SO2Me)(SO2Ph)

The title complex, obtained by co-crystallization of its molecular components from methanol, was characterized by low-temperature X-ray diffraction. The crystal structure (triclinic, space group P1, Z = 2) consists of two monomeric and crystallographicall

Nickel-Catalyzed Desulfitative Suzuki-Miyaura Cross-Coupling of N,N-Disulfonylmethylamines and Arylboronic Acids

A nickel-catalyzed approach for the synthesis of biaryl compounds from N,N-disulfonylmethylamines and arylboronic acids has been developed. Instead of arenesulfonyl chlorides, various N,N-disulfonylmethylamines were used as the aryl source through extrusion of SO2 to give cross-coupling products in moderate to good yields. A NiCl2(dppp)-catalyzed [dppp = 1,3-bis(diphenylphosphino)propane] desulfitative Suzuki-Miyaura cross-coupling reaction between N,N-disulfonylmethylamines and arylboronic acids is described for the first time. The biaryl compounds are obtained in moderate to good yields.

Studies on alkyl-nitrogen bond formation via reductive elimination from monomeric palladium complexes in high oxidation state

Oxidation of a series of defined palladium(II) complexes bearing a bidentate ligand, and a methyl and an amidato substituent was carried out with the aim to gain a better understanding of the inherent requirements for C-N bond-formation from Pd complexes in high oxidation state. This work clarified the role of the individual nitrogen sources and has important implication for alkyl-nitrogen bond-forming reactions catalyzed by Pd. Copyright