2547-08-2Relevant articles and documents
Facile Enzymatic Synthesis of Phosphorylated Ketopentoses
Wen, Liuqing,Huang, Kenneth,Liu, Yunpeng,Wang, Peng George
, p. 1649 - 1654 (2016/03/15)
An efficient and convenient platform for the facile synthesis of phosphorylated ketoses is described. All eight phosphorylated ketopentoses were produced using this platform starting from two common and inexpensive aldoses (d-xylose and l-arabinose) in more than 84% isolated yield (gram scale). In this method, reversible conversions (isomerization or epimerization) were accurately controlled toward the formation of desired ketose phosphates by targeted phosphorylation reactions catalyzed by substrate-specific kinases. The byproducts were selectively removed by silver nitrate precipitation avoiding the tedious and time-consuming separation of sugar phosphate from adenosine phosphates (ATP and ADP). Moreover, the described strategy can be expanded for the synthesis of other sugar phosphates.
Diastereoselektive, enzymatische Aldoladditionen mit L-Rhamnulose- und L-Fuculose-1-phosphat-Aldolasen aus E. coli
Fessner, Wolf-Dieter,Sinerius, Gudrun,Schneider, Achim,Dreyer, Matthias,Schulz, Georg E.,et al.
, p. 596 - 599 (2007/10/02)
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