25522-55-8

Basic information

• Product Name: 3-phenyl-2-cyclopropyl-1-propene
• Synonyms: 3-phenyl-2-cyclopropyl-1-propene
• CAS NO: 25522-55-8
• Molecular Weight: 158.243
• Mol File: 25522-55-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-phenyl-2-cyclopropyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenyl-2-cyclopropyl-1-propene(25522-55-8)
• EPA Substance Registry System: 3-phenyl-2-cyclopropyl-1-propene(25522-55-8)

Safety Data

• Hazardous Substances Data: 25522-55-8(Hazardous Substances Data)

Upstream product

• 6746-94-7 Cyclopropylacetylene 
• 100-44-7 benzyl chloride 
• 186581-53-3 diazomethane 
• 16079-66-6 2-benzyl-1,3-butadiene 
• 4663-22-3 isopropenylcyclopropane 
• 118-92-3 anthranilic acid 

Relevant articles and documents

Reductive hydrobenzylation of terminal alkynesviaphotoredox and nickel dual catalysis

A photoredox/nickel dual catalyzed reductive hydrobenzylation of alkynes and benzyl chlorides by employing alkyl amines as a stoichiometric reductant is described. This synergistic protocol proceedsviaMarkovnikov-selective migratory insertion of an alkyne into nickel hydride, followed by cross-coupling with benzyl chloride, providing facile access to important 1,1-disubstituted olefins. This reaction enables the generation of nickel hydride by utilizing readily available alkyl amines as the hydrogen source. The mild conditions are compatible with a wide range of aryl and alkyl alkynes as well as chlorides.