25643-78-1Relevant articles and documents
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Lavayssiere et al.
, p. C59 (1978)
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Guanidines as a nitrogen source for direct conversion of epoxides to aziridines
Tsuchiya, Yukiko,Kumamoto, Takuya,Ishikawa, Tsutomu
, p. 8504 - 8505 (2007/10/03)
Direct conversion of epoxides to aziridines was achieved with guanidines as a nitrogen source. Stereochemical inversion at the chiral centers of epoxides was observed without loss of optical purity.
Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts
Corriu, R. J. P.,Lanneau, Gerard F.,Mehta, V. D.
, p. 9 - 26 (2007/10/02)
Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes.A comparison is made with the corresponding reactions of tetracoordinated species.Decompositon of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal β-elimination.