2567-62-6Relevant articles and documents
Visible-Light-Driven Aryl Migration and Cyclization of α-Azido Amides
Liang, Siyu,Wei, Kaijie,Lin, Yajun,Liu, Tuming,Wei, Dian,Han, Bing,Yu, Wei
supporting information, p. 4527 - 4531 (2021/06/28)
This paper reports two new visible-light-promoted radical reactions of α-azido amides. By catalysis of [Ir(ppy)2(dtbbpy)]PF6 with i-Pr2NEt as the reducing agent, N-aryl α-azido tertiary amides were first converted to the corresponding aminyl radicals through reduction of the azido group; the aminyl radicals then underwent N-to-N aryl migration to give α-anilinyl-functionalized amides. α-Azido secondary amides, on the other hand, reacted with the solvent ethanol and i-Pr2NEt to afford the imidazolinone products.
Synthesis of α-amino acid amides: Ruthenium-catalyzed amination of α-hydroxy amides
Zhang, Min,Imm, Sebastian,Baehn, Sebastian,Neumann, Helfried,Beller, Matthias
supporting information; experimental part, p. 11197 - 11201 (2012/02/03)
Give me an N: The catalytic amination of α-hydroxy amides with a variety of amines, including anilines, primary and secondary aliphatic amines, and ammonia, yields a wide range of α-amino amides (see scheme). This atom-efficient amination protocol proceeds efficiently in the presence of a commercially available [Ru3(CO)12]/DCPE catalyst system. Copyright
Reaction of Azides in Presence of Aluminium Chloride
Ananthanarayanan, C.,Ramakrishnan, V. T.
, p. 156 - 157 (2007/10/02)
Amidoalkylazides (2) on treatment with aluminium chloride in benzene yield 2-anilino-N-(aryl)acetamides (3) in good yields.
