258885-12-0Relevant articles and documents
Synthesis, characterisation and ligand properties of a new amphiphilic triphenylphosphine analogue
Karlsson, Magnus,Johansson, Maria,Andersson, Carlaxel
, p. 4187 - 4192 (2007/10/03)
{4-[Bis(2-diethylaminoethyl)aminomethyl]diphenyl}phosphine, N3P, an analogue of triphenylphosphine (TPP) with amphiphilic character, was synthesized and characterised. Its metal complexes [Rh(CO)(N3P)(acac)] and cis-[PtCl2(NSP)2] have been prepared and the crystal structure of the former determined. The feasibility of catalysts formed in situ from [Rh(CO)2(acac)] and N3P in the hydroformylation of 1-hexene under homogeneous and biphasic conditions is also demonstrated. The Royal Society of Chemistry 1999.