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2605-79-0

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2605-79-0 Usage

Chemical Properties

Liquid

Uses

Different sources of media describe the Uses of 2605-79-0 differently. You can refer to the following data:
1. Barlox(R) 10S is a decyl amine oxide surfactant. Barlox(R) 10S provides superior coupling power without excessive foam.
2. N,N-Dimethyldecylamine N-oxide

Definition

ChEBI: A N-oxide of N,N-dimethyldecan-1-amine.

Flammability and Explosibility

Nonflammable

Check Digit Verification of cas no

The CAS Registry Mumber 2605-79-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,6,0 and 5 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 2605-79:
(6*2)+(5*6)+(4*0)+(3*5)+(2*7)+(1*9)=80
80 % 10 = 0
So 2605-79-0 is a valid CAS Registry Number.
InChI:InChI=1/C12H27NO/c1-4-5-6-7-8-9-10-11-12-13(2,3)14/h4-12H2,1-3H3

2605-79-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name decylamine-N,N-dimethyl-N-oxide

1.2 Other means of identification

Product number -
Other names N,N-Dimethyldecylamine oxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Surfactants
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2605-79-0 SDS

2605-79-0Synthetic route

N,N-dimethyldecylamine
1120-24-7

N,N-dimethyldecylamine

N,N-dimethyldecylamine-N-oxide
2605-79-0

N,N-dimethyldecylamine-N-oxide

Conditions
ConditionsYield
With dihydrogen peroxide; benzonitrile; Mg-Al-O-t-Bu HT (Catalyst B) In methanol; water at 65℃; for 0.5h; Product distribution / selectivity;98%
With dihydrogen peroxide; layered double hydroxide WO4(2-) at 20℃; for 2.5h;97%
With dihydrogen peroxide In methanol; water75%
With 1-decyl-4-(trifluoromethyl)pyrimidinium triflate; dihydrogen peroxide In aq. phosphate buffer; chloroform at 25℃; for 24h; Green chemistry; chemoselective reaction;67%
N,N-dimethyldecylamine-N-oxide
2605-79-0

N,N-dimethyldecylamine-N-oxide

C12H27NO*I2
104586-03-0

C12H27NO*I2

Conditions
ConditionsYield
With iodine In dichloromethane at 20℃; Thermodynamic data; -ΔG0;
With iodine In dichloromethane

2605-79-0Upstream product

2605-79-0Downstream Products

2605-79-0Relevant articles and documents

Two-Phase Oxidations with Aqueous Hydrogen Peroxide Catalyzed by Amphiphilic Pyridinium and Diazinium Salts

Hartman, Tomá?,?turala, Ji?í,Cibulka, Radek

, p. 3573 - 3586 (2016/01/25)

Amphiphilic pyridinium and diazinium salts were shown to be effective catalysts in two-phase (water/chloroform or water/dichloromethane) sulfoxidations and N-oxidations with hydrogen peroxide under mild conditions. This unprecedented oxidation method utilizes covalent bonding of hydrogen peroxide to a simple pyridinium or diazinium nucleus to increase the lipophilicity of the hydroperoxide species and to subsequently activate it for oxidations in a non-polar medium. The catalytic efficiency was found to depend on the type of heteroarenium core and on the lipophilicity of the catalyst. Five series of heteroarenium catalysts were prepared and investigated: 1-Alkyl-3,5-dicyanopyridinium, 1-alkyl-3,5-dinitropyridinium, 1-alkyl-3-cyanopyrazinium, 1-alkyl-4-cyanopyrimidinium and 1-alkyl-4-(trifluoromethyl)pyrimidinium triflates (alkyl=butyl, hexyl, octyl, decyl, dodecyl and hexadecyl). Among them, the 1-octyl-3,5-dinitropyridinium and 1-decyl-4-(trifluoromethyl)pyrimidinium triflates were found to be superior catalysts, showing the best stability and the highest catalytic activity, achieving acceleration by a factor of 350 relative to the non-catalyzed reaction. In contrast to other organocatalytic two-phase oxidations that use hydrogen peroxide, the presented method is characterized by high chemoselectivity and low catalyst loading (5mol%) and with the reactions being performed under mild conditions, that is, at 25 C using diluted hydrogen peroxide and a non-basic aqueous phase. The catalysts have simple structures and are readily available from commercial materials. Practical applications are demonstrated via the oxidation of several types of sulfides and amines.

The first example of catalytic N-oxidation of tertiary amines by tungstate-exchanged Mg-Al layered double hydroxide in water: A green protocol

Choudary,Bharathi,Venkat Reddy,Lakshmi Kantam,Raghavan

, p. 1736 - 1737 (2007/10/03)

A green process, using a recyclable tungstate-exchanged Mg-A1 layered double hydroxide (LDH-WO42-) heterogenised catalyst and aqueous H2O2 oxidant in water, leads to N-oxidation of aliphatic tert-amines to amine N-oxides in quantitative yields, at a high rate at room temperature.

AMINE OXIDES-XIII IODINE COMPLEXES WITH NON-AROMATIC AMINE OXIDES

Devinsky, F.,Leitmanova, A.,Lacko, I.,Krasnec, L.

, p. 5707 - 5710 (2007/10/02)

EDA-iodine complex with trialkylamine oxides in dichloromethane have been investigated spectrophotometrically.Thermodynamic (KADc,-ΔG0) and spectral (ΕADλ) characteristics of these complexes were determined.The absorption band of iodine in the visible region was blue-shifted with a variable maximum, depending on the structure of the amine oxide.The KADc and ΕADλ values were calculated using a modified method.A non-linear relationship KADc=(R), where R is the number of carbon atoms in the alkyl chain, was found.

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