26105-63-5Relevant articles and documents
Reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide
Levanova,Grabel'nykh,Kolesnikov,Klyba,Zhanchipova,Albanov,Russavskaya,Korchevin
experimental part, p. 988 - 992 (2011/02/26)
The reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide gave ethyltellanyl derivatives as a result of replacement of one chlorine atom in the substrate by tellurium, and of the other, by hydrogen. Probable mechanisms of reduction of the C-Cl bond and mass spectra of the products were considered. The mass spectra of ditelluroacetals revealed unusual rearrangement of the molecular ion, leading to the formation of Te-Te and new C-C bond.
Reaction of Mono- and Dihaloalkanes with Mixed Solutions of Chalcogens in Alkaline Reductive Systems
Deryagina,Grabel'nykh,Mamaseva
, p. 711 - 714 (2007/10/03)
Sufur-selenium, sulfur-tellurium, selenium-tellurium, and sulfur-selenium-tellurium mixtures readily dissolve in the hydrazine hydrate-alkali system to form chalcogenide anions. Alkylation of the latter with ethyl bromide results in preferential formation
