26110-93-0

Basic information

• Product Name: 1-Chlor-4-(2,2-dimethylpropyl)benzol
• Synonyms: 1-Chlor-4-(2,2-dimethylpropyl)benzol
• CAS NO: 26110-93-0
• Molecular Weight: 182.693
• Mol File: 26110-93-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-Chlor-4-(2,2-dimethylpropyl)benzol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Chlor-4-(2,2-dimethylpropyl)benzol(26110-93-0)
• EPA Substance Registry System: 1-Chlor-4-(2,2-dimethylpropyl)benzol(26110-93-0)

Safety Data

• Hazardous Substances Data: 26110-93-0(Hazardous Substances Data)

Upstream product

• 507-20-0 tertiary butyl chloride 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 594-19-4 tert.-butyl lithium 
• 104-88-1 4-chlorobenzaldehyde 
• 132381-66-9 C₂₀H₁₅ClOS 
• 68525-41-7 DL-3,4-Bis(4-chlorphenyl)-2,2,5,5-tetramethylhexan 
• 343844-08-6 meso-3,4-Bis(4-chlorphenyl)-2,2,5,5-tetramethylhexan 
• 6200-21-1 (+/-)-2,2-dimethyl-1-(p-chlorophenyl)propan-1-ol 
• 106-39-8 bromochlorobenzene 
• 3282-30-2 pivaloyl chloride 
• 1007-26-7 (2,2-dimethyl-1-propyl)benzene 
• 927-83-3 di-t-butyldiazene 
• 106-43-4 para-chlorotoluene 
• 108-88-3 toluene 

Downstream Products

• 6200-21-1 1-(4-Chlor-phenyl)-2,2-dimethyl-propan-1-ol 
• 26110-91-8 1-tert-Butyl-4-(2,2-dimethylpropyl)benzol 

Relevant articles and documents

Radical Substitution on the Sulphur of Thioester Group

Intermolecular reaction of an organo-radical with thioester gives the sulphide, which is formed by the sulphur centred substitution of acyl groups with a nucleophilic organo-radical, but no displacement of S-alkyl groups with the organo-radical takes place.

Chemistry of the tert-Butyl Radical: Polar Character, ρ Value for Reaction with Toluenes, and the Effect of Radical Polarity on the Ration of Benzylic Hydrogen Abstraction to Addition to Aromatic Rings

We have reexamined the reactions of tert-butyl radicals with toluenes and have obtained a ρ value of 0.49 +/- 0.04 at 80 deg C.The new, independent system involves the quantification of all of the principal products from the reaction of tert-butyl radicals with mixtures of toluene and substituted toluene.Five major products contain benzyl fragments and are formed in significant yields: two symmetrical bibenzyls, the cross bibenzyl, and the two neopentylbenzenes that result from combination of tert-butyl and the two benzyl radicals.Attack on the side chain is a major reaction of free tert-butyl radicals and is the only significant reaction that they undergo other than cage and termination reactions. tert-Butyl radicals do not add to the ring of toluenes.Data on the relative rates of addition to benzenes and hydrogen abstraction from toluenes are collected for a series of radicals including hydrogen atoms; methyl, isopropyl, and tert-butyl radicals; and p-nitrophenyl, p-bromophenyl, and phenyl radicals.The data demonstrate that more electrophilic radicals have a larger tendency to add to rings whereas more nucleophilic radicals have a larger tendency to abstract benzylic hydrogens.