261165-24-6

Basic information

• Product Name: (R)-2-Benzyloxyamino-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-methyl-butan-1-one
• Synonyms: (R)-2-Benzyloxyamino-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-methyl-butan-1-one
• CAS NO: 261165-24-6
• Molecular Weight: 420.573
• Mol File: 261165-24-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-2-Benzyloxyamino-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-methyl-butan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-Benzyloxyamino-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-methyl-butan-1-one(261165-24-6)
• EPA Substance Registry System: (R)-2-Benzyloxyamino-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-methyl-butan-1-one(261165-24-6)

Safety Data

• Hazardous Substances Data: 261165-24-6(Hazardous Substances Data)

Upstream product

• 75-30-9 2-iodo-propane 

Downstream Products

• 261165-25-7 [(1R)-2-methyl-1-[[(3aR,6S,7aS)-tetrahydro-8,8-dimethyl-2,2-dioxide-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl]carbonyl]propyl]carbamic acid 2,2-dioxide phenylmethyl ester 
• 1685-33-2 N-[(benzyloxy)carbonyl]-D-valine 

Relevant articles and documents

Highly diastereoselective radical addition to glyoxylic oxime ether: Asymmetric synthesis of α-amino acids

A high degree of stereocontrol in radical addition to the Oppolzer's camphor sultam derivative of glyoxylic oxime ether was achieved, providing a convenient method for preparing a variety of enantiomerically pure α-amino acids.

Asymmetric synthesis ofa-amino acids: Indium-mediated reactions of glyoxylic oxime ether in aqueous media

The indium-mediated allylation and alkylation reactions of the Oppolzer camphorsultam derivative of glyoxylic oxime ether proceeded with excellent diastereoselectivity in aqueous media, providing a variety of enantiomerically purea-amino acids.