262849-67-2 Usage
Functional groups
Bromo and cyano The presence of a bromine atom (bromo) and a cyano group (CN) in the molecule contributes to its reactivity and utility in chemical reactions.
Structure
2,3,4,6-Tetra-O-benzoyl-1-deoxy-beta-D-glucopyranosyl The compound has a core structure of a beta-D-glucopyranose ring, with four benzoyl groups attached to the 2, 3, 4, and 6 positions, and a cyanide group at the anomeric carbon (1-position).
Application
Building block in complex carbohydrate synthesis This compound is used as a starting material for the synthesis of complex carbohydrates and glycoconjugates, which are important biomolecules in living organisms.
Use in stereoselective glycosylation
The compound is often employed in organic chemistry and chemical biology as a reagent for the stereoselective glycosylation of various substrates, allowing for the formation of specific glycosidic bonds with high selectivity.
Hazardous and toxic properties
It is important to handle 2,3,4,6-Tetra-O-benzoyl-1-bromo-1-deoxy-beta-D-glucopyranosyl cyanide with care, as it can be hazardous and toxic if not used properly. This is due to the presence of the cyano group, which can release highly toxic hydrogen cyanide (HCN) upon hydrolysis or in the presence of acid.
Check Digit Verification of cas no
The CAS Registry Mumber 262849-67-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,6,2,8,4 and 9 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 262849-67:
(8*2)+(7*6)+(6*2)+(5*8)+(4*4)+(3*9)+(2*6)+(1*7)=172
172 % 10 = 2
So 262849-67-2 is a valid CAS Registry Number.
262849-67-2Relevant articles and documents
Radical-mediated bromination of carbohydrate derivatives: Searching for alternative reaction conditions without carbon tetrachloride
Czifrák, Katalin,Somsák, László
, p. 8849 - 8852 (2007/10/03)
KBrO3-Na2S2O4 in CH2Cl2-H2O or PhCF3-H2O biphasic solvent systems was applied to the bromination of several monosaccharide derivatives having capto-datively