263165-80-6

Basic information

• Product Name: 3,3'-Bis-(2-methoxy-phenyl)-[1,1']binaphthalenyl-2,2'-diol
• CAS NO: 263165-80-6
• Molecular Weight: 498.578
• Mol File: 263165-80-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,3'-Bis-(2-methoxy-phenyl)-[1,1']binaphthalenyl-2,2'-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3'-Bis-(2-methoxy-phenyl)-[1,1']binaphthalenyl-2,2'-diol(263165-80-6)
• EPA Substance Registry System: 3,3'-Bis-(2-methoxy-phenyl)-[1,1']binaphthalenyl-2,2'-diol(263165-80-6)

Safety Data

• Hazardous Substances Data: 263165-80-6(Hazardous Substances Data)

Upstream product

• 142010-87-5 (±)?3,3'?dibromo?2,2'?bis(methoxymethyl)?1,1'?binaphthalene 
• 211734-50-8 2,2'-Bis-methoxymethoxy-3,3'-bis-(2-methoxy-phenyl)-[1,1']binaphthalenyl 
• 5720-06-9 2-Methoxyphenylboronic acid 

Relevant articles and documents

Design of bronsted acid-assisted chiral Lewis acid (BLA) catalysts for highly enantioselective Diels-Alder reactions

Bronsted acid-assisted chiral Lewis acid (BLA) was highly effective as a chiral catalyst for the enantioselective Diels-Alder reaction of both α- substituted and α-unsubstituted α,β-enals with various dienes. Hydroxy groups in optically active binaphthol derivatives and boron reagents with electron-withdrawing substituents were used as Bronsted acids and Lewis acids, respectively. Intramolecular Bronsted acids in a chiral BLA catalyst played an important role in accelerating the rate of Diels-Alder reactions and in producing a high level of enantioselectivity. In particular, excellent enantioselectivity was achieved due to intramolecular hydrogen bonding interaction and attractive π-π donor-acceptor interaction in the transition-state assembly by hydroxy aromatic groups in a chiral BLA catalyst.