26557-56-2

Basic information

• Product Name: Indolizine, 7-methyl-2-phenyl-
• CAS NO: 26557-56-2
• Molecular Formula: C15H13N
• Molecular Weight: 207.275
• Mol File: 26557-56-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Indolizine, 7-methyl-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Indolizine, 7-methyl-2-phenyl-(26557-56-2)
• EPA Substance Registry System: Indolizine, 7-methyl-2-phenyl-(26557-56-2)

Safety Data

• Hazardous Substances Data: 26557-56-2(Hazardous Substances Data)

Upstream product

• 108-47-4 2,4-lutidine 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 1374515-52-2 (E)-ethyl 3-(7-methyl-2-phenylindolizin-3-yl)acrylate 
• 138611-54-8 tetramethyl 8-methyl-3-phenylazocino<2.1.8-cd>pyrrolizine-1,2,5,6-tetracarboxylate 
• 90626-29-2 4-Methyl-1-phenyl-9b-aza-benzo[cd]azulene-6,7,8,9-tetracarboxylic acid tetramethyl ester 
• 54377-47-8 6-Methyl-3-phenyl-pyrrolo[2,1,5-cd]indolizine-1,2-dicarboxylic acid dimethyl ester 
• 90456-31-8 6-Methyl-3-phenyl-1,2-dihydro-pyrrolo[2,1,5-cd]indolizine-1,2-dicarboxylic acid dimethyl ester 
• 138611-52-6 tetramethyl 5,9a-dihydro-8-methyl-3-phenylazocino<2.1.8-cd>pyrrolizine-1,2,5,6-tetracarboxylate 
• 90626-28-1 4-Methyl-1-phenyl-5a,9a-dihydro-9b-aza-benzo[cd]azulene-6,7,8,9-tetracarboxylic acid tetramethyl ester 
• 90456-38-5 (E)-2-(7-Methyl-2-phenyl-indolizin-3-yl)-but-2-enedioic acid dimethyl ester 

Relevant articles and documents

Regioselective C-H dithiocarbamation of indolizines with tetraalkylthiuram disulfide under metal-free conditions

An efficient and straightforward metal-free regioselective C-H dithiocarbamation of indolizines with tetraalkylthiuram disulfide has been described. A series of indolizine-dithiocarbamate derivatives were easily accessed in moderate to good yields with a broad scope. In addition, imidazo[1,2-a]pyridines were also well tolerated to afford diverse imidazoheterocycle-dithiocarbamate products, which are expected to be utilized for drug discovery. Of note, the reaction could be readily scaled up, and shows its practical value in organic synthesis.

Visible-Light-Induced Regioselective Dicarbonylation of Indolizines with Oxoaldehydes via Direct C-H Functionalization

A metal-free system for regioselective dehydrogenative cross-couplings between indolizines and oxoaldehydes catalyzed by visible light under mild conditions has been described. As an atom economical and eco-friendly protocol, the reaction proceeds in good yields using inexpensive, readily available visible-light sources and the environmentally friendly oxidant oxygen. Various valuable 1,2-dicarbonyl derivatives attached to an indolizine core were easily accessed by the direct dicarbonylation of the sp2 C-H bond.

Ruthenium-NHC-Catalyzed asymmetric hydrogenation of indolizines: Access to indolizidine alkaloids

Crossing N-bridges! A ruthenium/N-heterocyclic carbene (NHC) complex serves as the catalyst for the high-yielding and completely regioselective and asymmetric hydrogenation of substituted indolizines and 1,2,3-triazolo-[1,5-a] pyridines. This method shoul